Solid-state conversion of a MOF to a metal-organo polymeric framework (MOPF) via [2+ 2] cycloaddition reaction
IH Park, A Chanthapally, HH Lee, HS Quah… - Chemical …, 2014 - pubs.rsc.org
Chemical Communications, 2014•pubs.rsc.org
The bpeb ligands aligned in a slip-stacked manner in a two-fold interpenetrated non-porous
metal–organic framework (MOF)[Zn2 (bpeb)(bdc)(fa) 2] undergo [2+ 2] cycloaddition
reaction in a single-crystal to single-crystal manner to a non-interpenetrated 3D structure
with a new topology comprising an organic polymer ligand and a 2D coordination polymer.
metal–organic framework (MOF)[Zn2 (bpeb)(bdc)(fa) 2] undergo [2+ 2] cycloaddition
reaction in a single-crystal to single-crystal manner to a non-interpenetrated 3D structure
with a new topology comprising an organic polymer ligand and a 2D coordination polymer.
The bpeb ligands aligned in a slip-stacked manner in a two-fold interpenetrated non-porous metal–organic framework (MOF) [Zn2(bpeb)(bdc)(fa)2] undergo [2+2] cycloaddition reaction in a single-crystal to single-crystal manner to a non-interpenetrated 3D structure with a new topology comprising an organic polymer ligand and a 2D coordination polymer.
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