Supramolecular self-assembly of N-acetyl-capped β-peptides leads to nano-to macroscale fiber formation.

MP Del Borgo, AI Mechler, D Traore… - Angewandte …, 2013 - search.ebscohost.com
MP Del Borgo, AI Mechler, D Traore, C Forsyth, JA Wilce, MCJ Wilce, MI Aguilar
Angewandte Chemie International Edition, 2013search.ebscohost.com
From little things big things grow: 14‐Helical N‐acetyl β3‐peptides spontaneously self‐
assemble in a unique head‐to‐tail fashion to form fibers from solution. The fiber size can be
controlled from the nano‐to the macroscale. The inherent flexibility in design and ease of
synthesis provide powerful new avenues for the development of novel bio‐and
nanomaterials by supramolecular self‐assembly.
Abstract
From little things big things grow: 14‐Helical N‐acetyl β3‐peptides spontaneously self‐assemble in a unique head‐to‐tail fashion to form fibers from solution. The fiber size can be controlled from the nano‐to the macroscale. The inherent flexibility in design and ease of synthesis provide powerful new avenues for the development of novel bio‐and nanomaterials by supramolecular self‐assembly.
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