Chirality correction, asymmetry, ring‐chain tautomerism and hierarchical assemblies are
fundamental phenomena in nature. They are geometrically related and may impact the …

The de novo design of new peptide assemblies that expands the repertoire of biomaterial
nanostructures has been of a tremendous challenge. Hence, it is evident that a successful …

The capacity to design molecules capable of orchestrated movements in response to
specific stimuli could yield functional biomaterials suitable for diverse innovative materials …

Herein, we report the rich morphological and conformational versatility of a biologically
active peptide (PEP‐1), which follows diverse self‐assembly pathways to form up to six …

Using peptide assemblies with emergent properties to achieve elaborate functions has
attracted increasing attention in recent years. Besides tailoring the self‐assembly of peptides …

We describe the asymmetric synthesis of a highly substituted ω-octynoic acid derivative and
demonstrate its utility for generating complex macrocycles from unprotected peptides. The …

Peptides are excellent building units to construct supramolecular biomaterials for diverse
biomedical applications. A vast amount of research effort over the past two decades has …

The design and synthesis of β-sheet-based self-assembling cyclic peptides with tunable
cavities is described. The incorporation of a γ-amino acid with a hydroxyl group at C2 allows …

Cyclic peptides are important building blocks for forming functional structures and have
been applied in various fields. Considering the significant structural and functional roles of …

Owing to their diversity in size and shape, easy access, and biocompatibility, peptides are
versatile units for the construction of H-bonded tubular assemblies and other biomimetic …