Synthesis and pyrolysis mechanism of a novel polymeric precursor for SiBN ternary ceramic fibers

Y Liu, K Chen, S Peng, Y Cui, K Han, M Yu… - Ceramics …, 2019 - Elsevier
A novel polymeric precursor polyborosilazane (PBSZ) for SiBN ternary ceramic fibers was
successfully synthesized from trichlorosilane (HSiCl 3), boron trichloride (BCl 3) and …

A novel high yield polyborosilazane precursor for SiBNC ceramic fibers

C Zhang, K Han, Y Liu, S Mou, X Chang, H Zhang… - Ceramics …, 2017 - Elsevier
A novel processable and high yield polyborosilazane (PBSZ) precursor for SiBNC ceramic
fibers was synthesized via boron trichloride (BCl 3), co-polymerization of trichlorosilane …

Effects of hydrolysis of precursor on the structures and properties of polymer-derived SiBN ceramic fibers

Y Liu, K Chen, F Dong, S Peng, Y Cui, C Zhang… - Ceramics …, 2018 - Elsevier
In this paper, polyborosilazane precursor was synthesied from HMDZ, HSiCl 3, BCl 3 and
CH 3 NH 2 using a multistep method. By controlling the storage conditions, parts of the …

Fabrication and properties of precursor-derived SiBN ternary ceramic fibers

Y Liu, S Peng, Y Cui, X Chang, C Zhang, X Huang… - Materials & Design, 2017 - Elsevier
In this paper, polymer precursor polyborosilazane (PBSZ) was synthesized from
hexamethyldisilazane, HSiCl 3, BCl 3 and CH 3 NH 2 using a multi-step polymerization …

Influence of silicon sources on structures and properties of polyborosilazane precursor derived SiBNC ceramic fiber

L Yong, P Shuai, C Yongjie, Z Chenyu… - Ceramics …, 2018 - Elsevier
Different kinds of polyborosilazane (PBSZ) precursors for SiBNC ceramic fibers were
synthesized by SiCl 4/HSiCl 3/HSiMeCl 2 with BCl 3 and NH 3 CH 3 via a one-pot method …

Comparison of effects of nitrogen sources on the structures and properties of SiBNC ceramic fiber precursors

C Zhang, Y Liu, Y Cui, K Chen, S Peng, H Zhang… - Ceramics …, 2018 - Elsevier
Polyborosilazane synthesized from trichlorosilane (SiHCl 3), boron trichloride (BCl 3) and
methylamine (MeNH 2) is highly sensitive to moisture for hydrolysis of-NHMe unites and is …

One-pot synthesis of novel polyborosilazane to SiBNC fibres

Y Tang, J Wang, X Li, Z Xie, H Wang, Y Wang - Inorganic Chemistry …, 2009 - Elsevier
A processable N-methylpolyborosilazane was synthesised by an original method by using
boron trichloride (BTC), trichlorosilane (TCS) and heptamethyldisilazane (HpMDZ) as the …

Synthesis and characterization of polyborosilazane as novel precursor to SiBNC ceramic

Y TANG, J WANG, XD LI, WH LI, H WANG… - Acta Chimica …, 2008 - sioc-journal.cn
A novel soluble preceramic polymer to SiBNC ceramic, polyborosilazane (PBSZ), was
synthesized via a cocondensation approach with a yield of about 91%(w%) by using …

Large-scale preparation of SiBN ceramic fibres from a single source precursor

YQ Peng, KQ Han, X Zhao, MH Yu - Ceramics International, 2014 - Elsevier
Large-scale production of SiBN ceramic fibres was achieved by the pyrolysis of N-
methylpolyborosilazane. This precursor was prepared by a three-step synthesis starting from …

Synthesis and characterization of amorphous SiBNC ceramic fibers

S Mou, Y Liu, K Han, M Yu - Ceramics International, 2015 - Elsevier
A novel precursor for preparing SiBNC ceramic fibers was successfully prepared via co-
polymerization of trichlorosilane (SiHCl 3), boron trichloride (BCl 3) and methyl amine …