Intra-skeletal calcite in a live-collected Porites sp.: Impact on environmental proxies and potential formation process

CE Lazareth, C Soares-Pereira, E Douville… - … et Cosmochimica Acta, 2016 - Elsevier
Geochemical proxies measured in the carbonate skeleton of tropical coral Porites sp. have
commonly been used to reconstruct sea surface temperature (SST) and more recently …

CO2-water–basalt interaction. Low temperature experiments and implications for CO2 sequestration into basalts

AP Gysi, A Stefánsson - Geochimica et Cosmochimica Acta, 2012 - Elsevier
CO2-water–basaltic glass batch experiments were performed in order to study the feasibility
of low temperature CO2 sequestration into basalts including the key reactions and chemical …

Seawater pH, pCO2 and [CO2− 3] variations in the Caribbean Sea over the last 130 kyr: A boron isotope and B/Ca study of planktic foraminifera

GL Foster - Earth and Planetary Science Letters, 2008 - Elsevier
Here a new analytical methodology is described for measuring the isotopic composition of
boron in foraminifera using multicollector inductively coupled plasma mass spectrometry …

Barium isotope fractionation in the global barium cycle: First evidence from barium minerals and precipitation experiments

K von Allmen, ME Böttcher, E Samankassou… - Chemical Geology, 2010 - Elsevier
In this study, we present first results from an ongoing investigation on the stable barium (Ba)
isotope fractionation in the natural barium cycle. Stable Ba isotope signatures of …

Biogenic barium fluxes to the deep sea: Implications for paleoproductivity reconstruction

R Francois, S Honjo, SJ Manganini… - Global …, 1995 - Wiley Online Library
Dymond et al.(1992) have recently proposed an algorithm to reconstruct paleoproductivity
from biogenic Ba (bio‐Ba) accumulation rates in sediments. Their equation is based on …

First-principles study of boron speciation in calcite and aragonite

E Balan, F Pietrucci, C Gervais, M Blanchard… - … et Cosmochimica Acta, 2016 - Elsevier
Despite the importance of boron as a proxy of past ocean pH, the crystal-chemical factors
controlling its incorporation in the structure of calcium carbonates are still poorly understood …

[HTML][HTML] Theoretical isotopic fractionation between structural boron in carbonates and aqueous boric acid and borate ion

E Balan, J Noireaux, V Mavromatis, GD Saldi… - … et Cosmochimica Acta, 2018 - Elsevier
The 11 B/10 B ratio in calcite and aragonite is an important proxy of oceanic water pH.
However, the physico-chemical mechanisms underpinning this approach are still poorly …

Determination of B/Ca of natural carbonates by HR‐ICP‐MS

S Misra, M Greaves, R Owen, J Kerr… - Geochemistry …, 2014 - Wiley Online Library
We report a new method for HR‐ICP‐MS based accurate and precise B/Ca determination
from low mass natural carbonates (≤ 5 µg CaCO3), utilizing a mixed acid matrix (0.1 M …

Experimental and theoretical modelling of kinetic and equilibrium Ba isotope fractionation during calcite and aragonite precipitation

V Mavromatis, K van Zuilen, M Blanchard… - … et Cosmochimica Acta, 2020 - Elsevier
Barium isotope fractionation during calcite and aragonite inorganic precipitation was studied
in mixed flow reactors as a function of precipitation rate at 25° C and pH= 6.3±0.1. The …

Carbonate factories: a conundrum in sedimentary geology

L Pomar, P Hallock - Earth-Science Reviews, 2008 - Elsevier
Describing, characterizing and interpreting the nearly infinite variety of carbonate rocks are
conundrums–intricate and difficult problems having only conjectural answers–that have …