Fine-diameter Si–B–C–N ceramic fibers enabled by polyborosilazanes with N–methyl pendant group

X Ji, H Gao, S Zhang, Y Jia, MS Ji, X Zhou… - Journal of the European …, 2021 - Elsevier
Given the superior thermal stability and electromagnetic features, continuous Si–B–(C)–N
ceramic fibers have displayed great potential to fulfill the increasing demand for the high …

A novel high yield polyborosilazane precursor for SiBNC ceramic fibers

C Zhang, K Han, Y Liu, S Mou, X Chang, H Zhang… - Ceramics …, 2017 - Elsevier
A novel processable and high yield polyborosilazane (PBSZ) precursor for SiBNC ceramic
fibers was synthesized via boron trichloride (BCl 3), co-polymerization of trichlorosilane …

One-pot synthesis of novel polyborosilazane to SiBNC fibres

Y Tang, J Wang, X Li, Z Xie, H Wang, Y Wang - Inorganic Chemistry …, 2009 - Elsevier
A processable N-methylpolyborosilazane was synthesised by an original method by using
boron trichloride (BTC), trichlorosilane (TCS) and heptamethyldisilazane (HpMDZ) as the …

Synthesis and pyrolysis mechanism of a novel polymeric precursor for SiBN ternary ceramic fibers

Y Liu, K Chen, S Peng, Y Cui, K Han, M Yu… - Ceramics …, 2019 - Elsevier
A novel polymeric precursor polyborosilazane (PBSZ) for SiBN ternary ceramic fibers was
successfully synthesized from trichlorosilane (HSiCl 3), boron trichloride (BCl 3) and …

Influence of silicon sources on structures and properties of polyborosilazane precursor derived SiBNC ceramic fiber

L Yong, P Shuai, C Yongjie, Z Chenyu… - Ceramics …, 2018 - Elsevier
Different kinds of polyborosilazane (PBSZ) precursors for SiBNC ceramic fibers were
synthesized by SiCl 4/HSiCl 3/HSiMeCl 2 with BCl 3 and NH 3 CH 3 via a one-pot method …

A novel polyborosilazane for high-temperature amorphous Si–B–N–C ceramic fibres

WH Li, J Wang, ZF Xie, H Wang - Ceramics International, 2012 - Elsevier
Polyborosilazane synthesised from BCl3, HMeSiCl2, and Me3SiNHSiMe3 is easy to cross-
link for dehydrogenation of Si–H and N–H, which limits its practical applications for Si–B–N …

Fabrication and properties of precursor-derived SiBN ternary ceramic fibers

Y Liu, S Peng, Y Cui, X Chang, C Zhang, X Huang… - Materials & Design, 2017 - Elsevier
In this paper, polymer precursor polyborosilazane (PBSZ) was synthesized from
hexamethyldisilazane, HSiCl 3, BCl 3 and CH 3 NH 2 using a multi-step polymerization …

Chemistry, structure and processability of boron-modified polysilazanes as tailored precursors of ceramic fibers

L Gottardo, S Bernard, C Gervais… - Journal of materials …, 2012 - pubs.rsc.org
A series of boron-modified polysilazanes (BmPSs) of the type [B (C2H4SiCH3NCH3) 3] n
was synthesized by reaction of tris (dichloromethylsilylethyl) borane (B (C2H4SiCH3Cl2) 3 …

Boron-modified polysilazane as a novel single-source precursor for SiBCN ceramic fibers: synthesis, melt-spinning, curing and ceramic conversion

S Bernard, M Weinmann, P Gerstel, P Miele… - Journal of materials …, 2005 - pubs.rsc.org
A novel boron-modified polysilazane functionalised with Si-and N-bonded methyl groups
has been synthesised and characterised by means of FT-IR and NMR spectroscopies as …

Molecular design of melt-spinnable co-polymers as Si–B–C–N fiber precursors

A Viard, L Gottardo, D Lopez-Ferber… - Dalton …, 2017 - pubs.rsc.org
Two series of co-polymers with the general formula [B (C2H4SiCH3 (NH) x (NCH3) y) 3] n,
ie, composed of C2H4SiCH3 (NH) x and C2H4SiCH3 (NCH3) y (C2H4= CHCH3, CH2CH2) …