Optimal vulcanization of tires: Experimentation on idealized NR-PB natural and poly-butadiene rubber blends, phenomenological smoothed numerical kinetic model …

G Milani, F Milani - Polymer Testing, 2018 - Elsevier
An integrated simulation tool for the optimal vulcanization of tires is presented. Three are the
main issues discussed on the optimal vulcanization of 3D items with complex geometry …

Quasi-analytical kinetic model for natural rubber and polybutadiene rubber blends

G Milani, F Milani - Reaction Kinetics, Mechanisms and Catalysis, 2018 - Springer
A very simple kinetic model for natural rubber (NR) and polybutadiene (PB) blends is
presented. The model is characterized by a completely uncoupled curing between NR and …

Numerical kinetic model with regularization for NR–PB natural and poly-butadiene rubber blends: implementation and validation against experimental data

G Milani, F Milani - Journal of Mathematical Chemistry, 2019 - Springer
A simple and versatile numerical approach of experimental data regularization plus a kinetic
model to predict the vulcanization behavior in a rheometer for natural rubber (NR) and poly …

Rubber blends: kinetic numerical model by rheometer experimental characterization

G Milani, F Milani - Journal of Mathematical Chemistry, 2018 - Springer
A robust kinetic numerical model for natural rubber NR–poly-butadiene PB blends
vulcanized with sulfur is presented. For a preliminary experimental insight used then as …

Comprehensive kinetic numerical model for NR and high-cis poly-butadiene rubber blends

G Milani, F Milani - Chemical Engineering Transactions, 2017 - re.public.polimi.it
A simple but robust kinetic mathematical model to predict the mechanical/thermal behaviour
of NR and high-cis polybutadiene rubber blends is presented. The benchmark blend is a …

[HTML][HTML] Kinetic mathematical model with induction and reversion for the vulcanization of natural rubber and ethylene propylene diene monomer blend

G Pianese, G Milani, F Milani - Polymer Testing, 2024 - Elsevier
The complexity inherent in modeling and optimizing rubber cure processes stems from the
intricate interplay between “induction” and “reversion” phenomena. During the vulcanization …

Parabola-Hyperbola PH kinetic model for NR sulphur vulcanization

G Milani, F Milani - Polymer Testing, 2017 - Elsevier
Abstract A Parabola-Hyperbola (PH) kinetic model for NR sulphur vulcanization is
presented. The idea originates from the fitting composite Parabola-Parabola-Hyperbola …

Closed form numerical approach for a kinetic interpretation of high-cis polybutadiene rubber vulcanization with sulphur

G Milani, F Milani - Journal of Mathematical Chemistry, 2017 - Springer
A novel mathematical approach to predict the vulcanization degree of high-cis
polybutadiene rubber vulcanized with sulphur is presented. The model has kinetic base, it is …

[HTML][HTML] A novel approach for simulation and optimization of rubber vulcanization

J Lubura, P Kojić, J Pavličević, B Ikonić, D Balaban… - Polymers, 2023 - mdpi.com
The kinetic model, encompassing the curing and reversion phenomena of the NR/SBR
rubber vulcanization process, was developed by means of the finite element method …

Effective closed form starting point determination for kinetic model interpreting NR vulcanized with sulphur

G Milani, F Milani - Journal of Mathematical Chemistry, 2014 - Springer
In this paper, a closed form analytical approach for a recently presented kinetic model
proposed in Milani and Milani (Polym Test, 2013, under review) to interpret NR sulphur …