… the first enantioselective total syntheses of the hasubanan alkaloid (−)-metaphanine and the
norhasubanan alkaloid (+)-stephadiamine. … pathway of (+)-stephadiamine, we found that (−)-…

… and considered (+)-stephadiamine (1) as an ideal target to initiate our research program.
Shown in Scheme 1 is the retrosynthetic analysis of stephadiamine (1) featuring this strategic …

… (+)-Stephadiamine is an unusual alkaloid isolated from the vine … Here, we present the first
total synthesis of stephadiamine, which … Useful building blocks for the asymmetric synthesis of …

… Recently, an enantioselective dearomatizative Michael … synthetic strategy to facilitate the
total synthesis of all three sub-… The total synthesis of stephadiamine (9), the only example of a …

… Xestocyclamine A ((−)-1) is featured prominently in a biosynthesis pathway leading to a
large family of polycyclic alkaloids. The first total synthesis now proves that the structure of this …

… Elegant asymmetric synthesis of hasubanan alkaloids have … enantioselective total syntheses
of four representative members. The synthesis is characterized by catalytic enantioselective …

… hand, we then explored the asymmetric formation of (+)… overall yield. It is envisaged that the
use of the chiral azabicyclo[4.3.1] ring system (+)-7 will enable the asymmetric total synthesis …

We describe enantioselective total syntheses of cepharatines AD, members of the hasubanan
alkaloid family, which feature an unusual tetracyclic skeleton including an azabicyclo[3.3.1]…

… This decision paid valuable dividends, as it ultimately allowed compound 9 to be used as
a common intermediate for the total synthesis of nominal xestocyclamine A ((−)-3) and ent-…

… employed for the asymmetric total synthesis of three … The synthesis started with preparation
of spirooxindole 2 in a … finished the first asymmetric total synthesis of stephadiamine. …