… (9) Such a bell-shaped free-energy dependence was … reaction free energy is the geminate
charge recombination (CR) … −ΔG CR < E rm and produces reverse and weaker effects in the …

… Because CR competes with the dissociation of the geminate … lifetimes may appear artificially
bell-shaped, even though … As relaxation takes place, the energy gap with the ground state …

… Confirmation of excited-state reductive electron transfer was only unambiguously obtained
… of the geminate radical pair formed upon bimolecular excited-state electron transfer, were …

… but also a bell-shaped free energy gap dependence … geminate CR in the excited donor–acceptor
complexes (DACs) is one of the reactions for which the bell-shaped FEG dependence …

… , dominated by the reverse reaction, was measured. The rate … the distant-dependent ET rate
gives the electron transfer rate … ,A) •- , in which electron transfer can occur with rate k act . ET …

… use the energy gap x as a distributed reaction coordinate, transitions from |1⟩ to |2⟩ occur
… reactions only if x = 0 but does not consider the dependence on T 2 and k 23 , and which we …

… Biological electron transfer reactions occur in the complex environments found within living
cells and rely on a sensitive balance of pH, ionicity, and solvent polarity in order to catalyze …

… the energy-wasting reverse electron transfer event increases only by … triad, this thermal charge
recombination step occurs with a time … The calculated HOMO–LUMO energy gap for these …

… This thesis is concerned with understanding dynamics of intramolecular transport, charge
transfer at intramolecular D/A interfaces, and the nature of charges and excited states which …

… bell-shaped dependence. (1) An explanation of the monotonic decrease of the CR rate constant
with an increase in the free-energy gap … Energy Gap Dependence from that of Geminate …