Molecular structure elucidation with charge-state control

S Fatayer, F Albrecht, Y Zhang, D Urbonas, D Peña… - Science, 2019 - science.org
… monoxide–functionalized tips revealed changes in the … , we investigate the charge state–dependent
change of aromaticity … as bilayer NaCl, in which tunneling to the substrate and STM …

The control of intramolecular through-bond and through-space coupling in single-molecule junctions

Z Tan, W Jiang, C Tang, LC Chen, L Chen… - CCS …, 2022 - chinesechemsoc.org
… When the D unit shows stronger aromaticity, we expect to see … , showing a larger intramolecular
barrier to tunneling. Combined … suggest that modification of the intramolecular barrier can …

[HTML][HTML] Electrostatic control over temperature-dependent tunnelling across a single-molecule junction

AR Garrigues, L Wang, E Del Barco… - Nature communications, 2016 - nature.com
… case in the absence of intramolecular charge relaxation), coherent … In conclusion, our
measurements reveal a complex … the high chances for the molecule to change its conformation. …

Structure controlled long-range sequential tunneling in carbon-based molecular junctions

A Morteza Najarian, RL McCreery - ACS nano, 2017 - ACS Publications
barrier defined by the HOMO–LUMO gap, and not by charge … Figure 1b shows the four
aromatic molecules used in the … modifications to common models for transport in molecular

Excited-state intramolecular proton transfer in the kinetic-control regime

ZY Liu, JW Hu, TH Huang, KY Chen… - Physical Chemistry …, 2020 - pubs.rsc.org
… , most of the ESIPT molecules with measurable barriers are in … The results reveal a significant
ESIPT barrier for both CPIQ-… , leading to proton tunnelling from a vibrationally excited level …

Controlling the conductance of single-molecule junctions with high spin filtering efficiency by intramolecular proton transfer

ZQ Wang, Y Li, X Niu, MZ Wei, MM Dong, GC Hu… - Organic …, 2019 - Elsevier
… the Epi molecule as well as the transmission pathway of tunneling … Although the barrier of
the second transition state is higher … bonds in the core molecule reveals a large change in the …

[HTML][HTML] Voltage-driven control of single-molecule keto-enol equilibrium in a two-terminal junction system

C Tang, T Stuyver, T Lu, J Liu, Y Ye, T Gao… - Nature …, 2023 - nature.com
… voltage by the scanning tunneling microscope break junction … (combined with the high kinetic
barrier) on the neutral PES (… analysis reveals the root cause of the dramatic change in the …

Conformation, and charge tunneling through molecules in SAMs

L Belding, SE Root, Y Li, J Park… - Journal of the …, 2021 - ACS Publications
… of the electric field within the tunneling barrier) and thus the … (and thus increased intramolecular
electronic coupling) on the … This series revealed that a change in thickness does not …

Transition from direct to inverted charge transport Marcus regions in molecular junctions via molecular orbital gating

L Yuan, L Wang, AR Garrigues, L Jiang… - Nature …, 2018 - nature.com
… solid-state molecular tunnel junction by means of intra-molecular orbital … Figure 1 shows a
molecular diode that acts as a molecular … of intramolecular orbital gating, we performed charge

Charge transfer and orbital level alignment at inorganic/organic interfaces: the role of dielectric interlayers

M Hollerer, D Lüftner, P Hurdax, T Ules, S Soubatch… - ACS …, 2017 - ACS Publications
charge depletion (blue) from the molecule, which shows that … with the experimentally
determined WF change (Table 1). In … a direct tunneling process through the molecular states rather …