Role of anions during the Cu underpotential deposition on Au (111): A microcalorimetric investigation
S Frittmann, R Schuster - The Journal of Physical Chemistry C, 2016 - ACS Publications
… coverages of Cu and sulfate during the first Cu UPD stage with … in the absence of coadsorption
the Peltier heat of Ag bulk … (111) in the presence of Cl – in acidic electrolytes. (17) Oxygen …
the Peltier heat of Ag bulk … (111) in the presence of Cl – in acidic electrolytes. (17) Oxygen …
C2. 10 Surface electrochemistry
JH Moore, ND Spencer - … and Physical Chemistry-3 Volume Set, 2020 - taylorfrancis.com
… of the heavy metal ions Tl, Hg and Pb on Ag, Au, Cu or Pt (see, … of coadsorbed anions, for
example, for the upd of Cu on Au(… Cu atoms as well as the Au substrate, water and Cl, Br or S (…
example, for the upd of Cu on Au(… Cu atoms as well as the Au substrate, water and Cl, Br or S (…
Experimental techniques and structure of the underpotential deposition phase
OA Oviedo, L Reinaudi, S Garcia, EPM Leiva… - … From Fundamentals and …, 2016 - Springer
… Cu /Au system and the authors concluded that co-adsorption of … anions hinder the formation
of a full monolayer of Ag on … of Cu deposited on Au(111) in the presence of Br − anions at …
of a full monolayer of Ag on … of Cu deposited on Au(111) in the presence of Br − anions at …
Probe the Dynamic Adsorption and Phase Transition of Underpotential Deposition Processes at Electrode–Electrolyte Interfaces
… × √3)R30 copper UPD adlayer with coadsorbed SO 4 2– while … with the phase transition
between the Cu UPD (√3 × √3)R30 … the existence of adsorbed sulfate during copper UPD …
between the Cu UPD (√3 × √3)R30 … the existence of adsorbed sulfate during copper UPD …
Important Electrosorption Reactions
R Adzic, N Marinkovic, R Adzic… - Platinum Monolayer …, 2020 - Springer
… , with UPD adlayers, coadsorption of anion and metal atoms … , viz., Au, Ag, and Cu. The optical
properties of submonolayers … At the most positive potential around 0.8 V, Br − is adsorbed …
properties of submonolayers … At the most positive potential around 0.8 V, Br − is adsorbed …
Underpotential deposition
OA Oviedo, L Reinaudi, SG García… - Monographs in …, 2016 - Springer
… the absence of anion cosorption or competitive sorption phenomena. However, Ag upd on
Au(111) … ¼ À478 mV) surfaces [64–66], therefore the presence of adsorbed anions cannot be …
Au(111) … ¼ À478 mV) surfaces [64–66], therefore the presence of adsorbed anions cannot be …
A phenomenological theory of electrosorption
GA Attard - Journal of Electroanalytical Chemistry, 2018 - Elsevier
… Cation adsorption will result in a co-adsorption layer in which … The answer lies in the fact
that if Γ on the LUMO of the Br − is … is transferred back from the metal to the iodide due to a …
that if Γ on the LUMO of the Br − is … is transferred back from the metal to the iodide due to a …
Fundamentals of metal deposition via surface limited redox replacement of underpotentially-deposited monolayer
SR Brankovic - The Electrochemical Society Interface, 2018 - iopscience.iop.org
… from the existence of one or more UPD ML superstructures22… the energetics of the anion
co-adsorption were found to be … 4 is always satisfied (Ag and Pd UPD MLs might be the only …
co-adsorption were found to be … 4 is always satisfied (Ag and Pd UPD MLs might be the only …
[HTML][HTML] Real–time observation of interfacial ions during electrocrystallization
M Nakamura, T Banzai, Y Maehata, O Endo, H Tajiri… - Scientific reports, 2017 - nature.com
… It is known that the coadsorbed anions in the Cu upd layer … The absence, or reduced presence,
of the (bi)sulfate anion … anions used in this study, are specifically adsorbed on the Ag, Cd, …
of the (bi)sulfate anion … anions used in this study, are specifically adsorbed on the Ag, Cd, …
Hydrogen and halide co-adsorption on Pt (111) in an electrochemical environment: a computational perspective
… stable co-adsorption structure of hydrogen with chlorine, bromine … This indicates that Pt acts
differently compared to Ag and Au as far … The presence of this hydrogen upd layer also has a …
differently compared to Ag and Au as far … The presence of this hydrogen upd layer also has a …