Dynamic Combinatorial Chemistry Out of Equilibrium
… of the most stable compounds (Figure 8.1a), allowing access to … , the reaction can trigger
selfreplicating behavior. An added … “dynamic kinetic stability” [87] and requires dissipative out-of-…
selfreplicating behavior. An added … “dynamic kinetic stability” [87] and requires dissipative out-of-…
[HTML][HTML] Dynamics Differences between Minimal Models of Second and First-Order Chemical Self-Replication
LA Moseley, E Peacock-López - Dynamics, 2023 - mdpi.com
… numerical integration, which allows for finding parameters and … trace to determine the SS’s
stability. For the three-variable case, … Using parameters selected from the previous bifurcation …
stability. For the three-variable case, … Using parameters selected from the previous bifurcation …
On the conditions for mimicking natural selection in chemical systems
… called dynamic kinetic stability (DKS) in replicating systems … by the equilibrium constant k i
/k −i rather than by kinetics and, … allow kinetic selection to play a role in the emergence of self-…
/k −i rather than by kinetics and, … allow kinetic selection to play a role in the emergence of self-…
Out‐of‐Equilibrium (Supra) molecular Systems and Materials: An Introduction
N Giuseppone, A Walther - Out‐of‐Equilibrium (Supra) …, 2021 - Wiley Online Library
… such as self-regulation, adaptation, evolution, and self-replication. … fuels, allows to reach
very unusual dynamics in the form of … Figure 1.1 Selected out-of-equilibrium systems in living …
very unusual dynamics in the form of … Figure 1.1 Selected out-of-equilibrium systems in living …
[HTML][HTML] Selection from a pool of self-assembling lipid replicators
I Colomer, A Borissov, SP Fletcher - Nature communications, 2020 - nature.com
… self-replicators kept out-of-equilibrium and (already well-explored) self-replication to a
thermodynamically stable … of chemical reactants is provided, allowing the consumption of 1 and 2a…
thermodynamically stable … of chemical reactants is provided, allowing the consumption of 1 and 2a…
Exploring the emergence of complexity using synthetic replicators
T Kosikova, D Philp - Chemical Society Reviews, 2017 - pubs.rsc.org
… limits imposed on selection processes in networks operating … that exploit dynamic systemic
resolution, non-equilibrium … ii) LG, which makes this complex significantly less stable in theory …
resolution, non-equilibrium … ii) LG, which makes this complex significantly less stable in theory …
From autocatalysis to survival of the fittest in self-reproducing lipid systems
MG Howlett, SP Fletcher - Nature Reviews Chemistry, 2023 - nature.com
… used to explore out-of-equilibrium systems and allow kinetic … being selected for under the
out-of-equilibrium conditions. e, Lipid … slower but are longer lived owing to their kinetic stability. …
out-of-equilibrium conditions. e, Lipid … slower but are longer lived owing to their kinetic stability. …
[HTML][HTML] How and why kinetics, thermodynamics, and chemistry induce the logic of biological evolution
… -equilibrium conditions, populations of chemical systems capable of exponential growth can
manifest another kind of stability, dynamic kinetic stability (… which allows selection toward life …
manifest another kind of stability, dynamic kinetic stability (… which allows selection toward life …
Autocatalysis: Kinetics, mechanisms and design
AI Hanopolskyi, VA Smaliak, AI Novichkov… - …, 2021 - Wiley Online Library
… The influence of the kinetics of autocatalysis on the selection … the dimer for parabolic kinetics;
if the equilibrium is shifted … forms a stable peroxide complex with copper, which enables the …
if the equilibrium is shifted … forms a stable peroxide complex with copper, which enables the …
From self-replication to replicator systems en route to de novo life
P Adamski, M Eleveld, A Sood, Á Kun… - Nature Reviews …, 2020 - nature.com
… must enable open-ended Darwinian evolution and the system must remain out of equilibrium,
in a state of dynamic kinetic stability… We consider here a selection of the most important self-…
in a state of dynamic kinetic stability… We consider here a selection of the most important self-…