… occurrence of different structural isomers of organic radical cations [43], Koopmans’ paradigm
… Simultaneous bridgelocalized and mixed-valence character in diruthenium radical cations …

… + displays a charge delocalized mixed-valence property as a … (E 2 ) decreased simultaneously
to more negative values, … with significant “bridge-localized” ground-state character, key …

… In general, the bridge-localized radical characteristics often correspond to a dominant non-…
Simultaneous bridge-localized and mixed-valence character in diruthenium radical cations …

… Simultaneously, a new strong band at ca. 850 nm emerged … bridged iron ethynylene and
ruthenium vinylene complexes 1 … the largest ΔE value found in ruthenium vinyl complex 2. In the …

… of central importance to study the mixed-valence (MV) electronic … the characters reflecting
the involvement of the conjugated (… accompanying the strongly bridge-localized oxidation of the …

… character. Finally, the third anodic waves in the voltammetric responses of the homo-bimetallic
complexes are associated with the concurrent … In recent years mixed-valence (MV) states …

… co-workers have shown that ruthenium complexes linked by α,… radical cation with a possibly
slightly larger metal character. (… A similar situation was observed for the iron mixed-valence …

… reported dinuclear mixed-valence ruthenium complexes with … the long distance between
ruthenium termini and the presence … to adopt partial vinylidene character upon oxidation to 2a + …

… -valence charge transfer analysis of mixed-valence states by the Marcus–… mixed-valence
states was mainly localized on the aryl bridge and NAr 2 and featured the less metal character …

… Conventionally, the electronic character of a mixed-valence complex … The simultaneous
existence of major and minor redox isomers … and mixed-valence characteristics in diruthenium …