Optical images of molecular vibronic couplings from tip-enhanced fluorescence excitation spectroscopy
… of such an effect will require both submolecule spatial resolution (for atomic motions) and …
We first calculate the vibrationally resolved absorption spectrum of H 2 P in the gas phase to …
We first calculate the vibrationally resolved absorption spectrum of H 2 P in the gas phase to …
Vibronic spectroscopy with submolecular resolution from STM-induced electroluminescence
… excitation … fluorescence measurements on ZnPc trapped in frozen matrices [16], these
emission lines are associated to the vibrational modes of the molecule and constitute an accurate …
emission lines are associated to the vibrational modes of the molecule and constitute an accurate …
[HTML][HTML] High-resolution vibronic spectroscopy of a single molecule embedded in a crystal
J Zirkelbach, M Mirzaei, I Deperasińska… - The Journal of …, 2022 - pubs.aip.org
… Δν = 1/(2πT 1 ) determined from pulsed measurements of the excited state lifetime T 1 = 7 ns
(… We also used fluorescence excitation spectroscopy to probe the vibrational levels of S 1 . …
(… We also used fluorescence excitation spectroscopy to probe the vibrational levels of S 1 . …
Single-molecule tautomerization tracking through space-and time-resolved fluorescence spectroscopy
B Doppagne, T Neuman, R Soria-Martinez… - Nature …, 2020 - nature.com
… and submolecular spatial resolution of the … excitation efficiency is larger when electron
tunnelling takes place through the HOMO. This is in agreement with the increased fluorescence …
tunnelling takes place through the HOMO. This is in agreement with the increased fluorescence …
Selective Excitation of Vibrations in a Single Molecule
… role of selectively exciting molecular vibrations in achieving precise control … excitation of the
vibrational modes by tuning the excitation … light-matter interactions at the sub-molecular level. …
vibrational modes by tuning the excitation … light-matter interactions at the sub-molecular level. …
First-principles study on vibrationally resolved fluorescence of fused 5, 15-(diphenyl)-10, 20-(dibromo) porphyrin molecule
F Qiu, C Song, L Li, Y Wei, G Tian - The Journal of Chemical Physics, 2018 - pubs.aip.org
… images of single porphyrin molecules with submolecular … also performed for the first singlet
excited state with TDDFT. Three … fluorescence spectra also made it possible for the accurate …
excited state with TDDFT. Three … fluorescence spectra also made it possible for the accurate …
Visualizing vibrational normal modes of a single molecule with atomically confined light
… ) 3,4 reaches the requisite sub-molecular spatial resolution 5 , … , with the corollary that both
excitation and detection proceed … Precise alignment of the parabolic mirror is established by …
excitation and detection proceed … Precise alignment of the parabolic mirror is established by …
Probing intramolecular vibronic coupling through vibronic-state imaging
… between the vibrational wavefunctions of the excited and ground … Molecular fluorescence
is generated by the excitation of … Also plotted are a DFT simulated fluorescence spectrum from …
is generated by the excitation of … Also plotted are a DFT simulated fluorescence spectrum from …
Excited-state imaging of single particles on the subnanometer scale
A Wallum, HA Nguyen… - Annual Review of Physical …, 2020 - annualreviews.org
… to supplement spectroscopy experiments with accurate calculations because of the … with
submolecular resolution (48). In this paper, STM-L was employed to spatially map the vibrational …
submolecular resolution (48). In this paper, STM-L was employed to spatially map the vibrational …
Submolecular-scale control of phototautomerization
A Rosławska, K Kaiser, M Romeo, E Devaux… - Nature …, 2024 - nature.com
… at excitation energies of hν in = 1.90 eV and hν in > 1.95 eV that can be linked to the resonant
excitation of the vibrational … tautomerization reaction with submolecular precision by tuning …
excitation of the vibrational … tautomerization reaction with submolecular precision by tuning …