Here, we report a silver-mediated coupling of acetylenes with sulfoximines to synthesize N-α-
ketoacyl sulfoximines and N-α, β-unsaturated acyl sulfoximines. The reactions are …

The first preparation of α‐ketoacyl sulfoximines under solvent‐free conditions using aryl
ethanones and NH‐sulfoximines has been discovered and a series of desired 2‐oxo‐2 …

We have introduced a sulfoximidation reaction initiated by visible light between α-phenyl
vinyl azides and NH-sulfoximines. The cost-effective and readily accessible hypervalent …

Abstract By using Mor‐DalPhos as the P, N‐bidentate ligand and mesylate as the counter
ion, the resulting gold (I) complex catalyzes efficient oxidative transformations of various …

From one starting material, two tandem reaction protocols to synthesize seven-and eight-
membered ring sultams were developed. One protocol employs intermolecular epoxide ring …

The silver hexafluoroantimonate/N-bromosuccinimide (NBS)-catalyzed synthesis of α-
alkylated aryl ketones with a tertiary carbon center from internal alkynes and benzyl alcohols …

Sulfonyl azides have been widely used as sulfonamido, diazo, and azido donors, as well as
all-nitrogen 1, 3-dipoles donors in synthetic chemistry. Here, the sulfonyl azides were used …

Methods to synthesize α‐substituted alkenyl sulfoxides are highly useful as they are widely
used to construct diverse molecules of high synthetic importance. We have described a …

Here, we are reporting a multicomponent cascade reaction approach for the synthesis of β-
keto sulfones by exploiting differential reactivity pattern of substrates under open …

Gold-catalyzed reactions between sulfenamides and terminal alkynes proceeded via cis-
insertion of alkynes into the N–S bond in sulfenamides, affording the corresponding β …