An asymmetric synthesis of (+)-stephadiamine has been accomplished featuring (a) an
enantioselective dearomatizative Michael addition to generate a quaternary stereocenter;(b) …

The enantioselective total synthesis of madangamine E has been completed in 30 steps,
enabled by a new catalytic and highly enantioselective desymmetrizing intramolecular …

A stereocontrolled synthesis of β2, 3-amino amides is reported. Innovation is encapsulated
by the first use of nitroalkenes to achieve double umpolung in enantioselective β-amino …

Highly enantioselective synthesis of acyclic α-tertiary amines through asymmetric
desymmetrization is reported. This approach is based on chiral phosphoric acid mediated …

We report the first enantioselective total syntheses of the hasubanan alkaloid (−)-
metaphanine and the norhasubanan alkaloid (+)-stephadiamine. Key features of these …

Condensation of tert-butyl (E)-3-(2′-aminophenyl) propenoate with a range of aromatic and
heteroaromatic aldehydes gives the corresponding imines as single diastereoisomers (> …

An enantioselective route to the C, D-bicycle of massadine is reported. Enantiopure
intermediates were generated by a single stereoselective reduction using the Corey–Bakshi …

The first enantioselective synthesis of (−)-himalensine A has been achieved in 22 steps. The
synthesis was enabled by a novel catalytic, enantioselective prototropic shift/furan Diels …

Concise asymmetric total syntheses of the fungal metabolites (−)-stephacidin A,(+)-
stephacidin B, and (+)-notoamide B are described. Key features of these total syntheses …

An asymmetric total synthesis of (−)-epibatidine (1), isolated from the skin of the Ecuadorian
poison frog, Epipedobates tricolor, of the family Dendrobatidae, has been achieved by virtue …