Enantioenriched 2-azabicyclo [3.1. 0] hexanes are accessed from readily available allyl
substituted α-isocyanoesters by intramolecular (1+ 2) cycloaddition with the olefinic moiety …

A highly enantioselective copper-catalyzed [3+ 2] cycloaddition reaction of α-isocyanoesters
with β, β-disubstituted enones has been developed. Dihydropyrroles were obtained in …

Heterocyclic compounds containing a chiral pyrrolidine motif commonly appear in natural
alkaloids and pharmaceutically active substances, and serve as building blocks commonly …

A highly selective and practical asymmetric Ag (I) catalyst system has been developed for
the [3+ 2] cycloaddition reactions between isocyanoacetates and cyclopentenediones. The …

In addition: A copper/N‐heterocyclic carbene (NHC)‐catalyzed 1, 4‐addition of
organoboronates to alkylidene cyanoacetates was developed, in which the catalytic cycle is …

A highly diastereo-and enantioselective BOX/Cu (II)-catalyzed C2, C3-cyclopentannulation
of indoles with donor–acceptor cyclopropanes has been developed on the basis of …

A highly diastereo-and enantioselective desymmetrization of prochiral cyclopropenes via a
Cu (CH3CN) 4BF4/Ph-Phosferrox complex catalyzed 1, 3-dipolar cycloaddition of …

We report herein the first example of conjunctive C–C cross-coupling of cyclopropenes
enabled by a Cu-catalyzed three-component reaction of organoboron, cyclopropene and …

Enabled by a commercial bisphosphine ligand, the Cu-catalyzed three-component
cyclopropene alkenylamination with alkenyl organoboron reagent and hyroxyamine esters …

We describe herein an intriguing method for the synthesis of biaryl aldehydes bearing both
axial and central chirality through a desymmetric [3+ 2] cycloaddition reaction of activated …