… aryl aldehydes 11 have been synthesized by oxidation of … -catalyzed aerobic oxidation
of propargyl alcohols to ynones … have given access to ynones via C–N bond cleavage. (188) …

… aerobic oxidation of alkanes in the presence of an aldehyde … Cu(acac)2 to give the
corresponding ynones (Scheme 2.24). … aerobic oxidative cleavage of the C═C double bond under …

… aldehydes, the formation of aliphatic acyl radicals via alkyl aldehyde C(sp 2 )–H bond cleavage
… radicals generated by the oxidation of aliphatic aldehydes under heated conditions can …

… C–C bond cleavage involves 1,3-O/C migration and aerobic … 2 direct from benzylamines 4
and ynones 5 was adopted to … )-one products 2 were formed by the aerobic oxidation of 1,5-…

… C–C bond cleavage and a Kornblum-type oxidation of … 139 and α,β-unsaturated aldehydes
142 by a combination of the … In addition to ynones, ynamides 195a and ynoates 195b–c …

… ; (2) the oxidation of propargylic position in … aldehydes relies on the homolytic cleavage of
the C–H bond. The groups of Wei, Yu, and Li described independently the synthesis of ynones …

… carbaglucoses react by pseudoglycosidic bond cleavage via an SN1 process in … The aerobic
oxidation of benzylamine to N-… The 3 + 2 annulation of ynones and aminocrotonates gives …

… and the key to induce the consecutive CC bond cleavage. We also synthesized aldehyde
58a and 59a. When aldehyde 58a was reacted under standard condition, product 58b was …

… of the aldehyde and α-C of enamines, and oxidative … reaction of trifluoromethyl-α,β-ynones
with β-enamino esters or β-… In this aerobic oxidation reaction, using molecular oxygen as the …

… , ynoates, and ynones 5 was achieved by the same group via … alkenyl aldehydes were
afforded via ring-opening allylation. … reaction was performed under aerobic condition, peroxide …