Isoreticular crystallization of highly porous cubic covalent organic cage compounds

S Ivanova, E Köster, JJ Holstein… - Angewandte Chemie …, 2021 - Wiley Online Library
… measurements revealed exceptionally high surface areas up … To assess permanent porosity,
we measured N 2 sorption at … covalent organic cages with alternating micro- and mesopores

Reticular chemistry in the construction of porous organic cages

K Su, W Wang, S Du, C Ji, M Zhou… - … of the American Chemical …, 2020 - ACS Publications
… it is difficult to crystallize such large “porous” cages, and it is also … such large organic cages
robust and permanently porous, … The high surface areas of such cages may have the ability to …

Porous organic cages

X Yang, Z Ullah, JF Stoddart, CT Yavuz - Chemical Reviews, 2023 - ACS Publications
… features of low density, large surface area, high thermal insulation, and … mesopores in the
solids allow faster degradation. … Cage-coated GC columns exhibit extremely high selectivity …

Cage based crystalline covalent organic frameworks

JX Ma, J Li, YF Chen, R Ning, YF Ao… - Journal of the …, 2019 - ACS Publications
… The cage-COFs have a permanent porosity and can adsorb CO 2 facilitated by the intrinsic
cage 2 is almost nonporous as revealed by a very small BET surface area (4 m 2 g –1 ). The …

Elucidating heterogeneous photocatalytic superiority of microporous porphyrin organic cage

C Liu, K Liu, C Wang, H Liu, H Wang, H Su, X Li… - Nature …, 2020 - nature.com
… N 2 sorption experiment at 77 K was conducted to identify the permanent porosity of cage-…
Brunauer–Emmett–Teller surface area of 112 m 2 g –1 (Fig. 3). The large pore size of 1.35 and …

Permanently microporous metal–organic polyhedra

AJ Gosselin, CA Rowland, ED Bloch - Chemical reviews, 2020 - ACS Publications
… by MOFs, the highest surface area for a porous coordination cage was recently reported as
… chromium(II) MOPs display exceptionally high thermal stabilities and surface areas. The …

Covalent organic cages in catalysis

P Bhandari, PS Mukherjee - ACS Catalysis, 2023 - ACS Publications
high surface area per unit volume, which is associated with … in 0.7 min with an extremely
high turnover frequency (TOF) … UV–vis results displayed a high rate constant (k = 1.25 min –…

Stabilizing the Extrinsic Porosity in Metal–Organic Cages-Based Supramolecular Framework by In Situ Catalytic Polymerization

G Liu, M Zhou, K Su, R Babarao, D Yuan… - CCS …, 2021 - chinesechemsoc.org
… material retaining its crystallinity and permanent porosity. A … in other mesoporous materials,
19 – 21 such as metal–organic … This appears to be the highest surface area reported for MOC-…

Transformation of porous organic cages and covalent organic frameworks with efficient iodine vapor capture performance

C Liu, Y Jin, Z Yu, L Gong, H Wang, B Yu… - Journal of the …, 2022 - ACS Publications
… However, it is noteworthy that both the nitrogen-rich structure nature and high surface area
(… 2 adsorption uptakes for USTB-3 and USTB-3c possessing very different BET surface areas. …

Permanent Porosity in Hydroxamate Titanium–Organic Polyhedra

B Lerma-Berlanga, J Castells-Gil… - Journal of the …, 2021 - ACS Publications
cage (cMUV-11) are also used to demonstrate the effect of pore chemistry in accessing high
surface areas … Tezcan to design a 3D framework built from exceptionally stable [Fe 4 (m-H 2 …