… ligands was then well-demonstrated by the cyclopentadienyl (Cp) based Dy(III)SMM.[24] For
such SMMs the distance from the ring … [24] Represented by the Cp based ligands lanthanide …

… valence orbitals, eg (n + 1)s, (n + 1)p, and nd orbitals, for the efficient orbital overlap, and
sterically encumbered ligands to preclude the coordination of other ligands to the metal centre. …

… for cyclopentadienyl Dy III complexes in comparison with other ligands based on organometallic
rings), … tool to expand our description of ligand field effects in lanthanide-based SMMs. …

… magnetic capabilities and synthetic matters of lanthanoid complexes based on cyclopentadienyl
ligands… ]-- ligand are first introduced and then the magnetic capabilities of dysprosium …

… lanthanide single-molecule magnets (SMMs) have progressively evolved in recent years.
Lanthanide … and symmetry of the ligand field environment about the magnetic metal centre as …

… known as an "umbrella review" on lanthanide-based single-molecule magnets (4f-SMM). As
a … A particular focus in pointed toward ligands adapted to divalent and tetravalent lanthanide …

… literature blocking temperatures it was speculative whether such a complex would enable
higher blocking temperatures. One synthetic direction was to design bulky ligands to support a …

… For instance, aryl-substituted cyclopentadienyl ligands have … of lanthanoid-based
single-molecule magnets.The main … that can function as single-molecule magnets. Trivalent …

… cyclopentadiene-based rare earth monomolecular magnets. … bridge-linked rare earth
single-molecule magnet system. By … -linked ligand, they successfully achieved robust magnetic …

… The Dy(III) ion is placed in two bis(cyclopentadienyl) ligands environment with the large
negative charges in axial contribution leading to exceptional magnetic axiality, which is also …