Shining new light on multifunctional lanthanide singlemolecule magnets

R Marin, G Brunet, M Murugesu - … Chemie International Edition, 2021 - Wiley Online Library
… The design principles in the synthesis of luminescent lanthanide single-molecule magnets
(SMMs) are the focus of this Review. Although a number of luminescent SMMs have been …

Metal–metal bond in lanthanide single-molecule magnets

Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for developing high-…
single-molecule magnets (SMMs). The shift in research focus from increasing the magnetic

External stimuli modulate the magnetic relaxation of lanthanide single-molecule magnets

Z Zhu, XL Li, S Liu, J Tang - Inorganic Chemistry Frontiers, 2020 - pubs.rsc.org
… , eg combining magnetic properties with conductivity or optical phenomena. In the past 27
years or so, single molecule magnets (SMMs) and multifunctional magnetic materials have …

Photoluminescent Lanthanide (III) SingleMolecule Magnets in Three‐Dimensional Polycyanidocuprate (I)‐Based Frameworks

JJ Zakrzewski, S Chorazy… - … A European Journal, 2019 - Wiley Online Library
… The three-dimensional d–f cyanido-bridged network was shown to serve as an efficient
coordination scaffold to achieve emissive lanthanide single-molecule magnets. …

Electro-activity and magnetic switching in lanthanide-based single-molecule magnets

O Cador, B Le Guennic, F Pointillart - Inorganic Chemistry Frontiers, 2019 - pubs.rsc.org
… properties, such as magnetism and electrical conductivity, in … to Single Molecule Magnets
(SMMs) based on lanthanides. … on single-molecule magnets of lanthanides associated with …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
… the study of Single-Molecule Magnets (SMMs) for almost three decades. Although some
recent breakthroughs are mainly about the SMMs containing only one lanthanide ion, we …

Strong Relativistic Effects in Lanthanide-Based Single-Molecule Magnets

VD Dergachev, DD Nakritskaia… - The Journal of Physical …, 2022 - ACS Publications
Lanthanide-based single-molecule magnets (SMMs) are promising building blocks for quantum
memory and spintronic devices. Designing lanthanide… elements such as lanthanides. We …

Single-electron lanthanide-lanthanide bonds inside fullerenes toward robust redox-active molecular magnets

F Liu, L Spree, DS Krylov, G Velkos… - Accounts of chemical …, 2019 - ACS Publications
magnetic ions (6−9) are the two main strategies for improving the performance of single-molecule
magnets … endohedral metallofullerenes (EMFs) with lanthanide (Ln) ions. (10−13) High …

Lanthanide–radical single-molecule magnets: current status and future challenges

HD Li, SG Wu, ML Tong - Chemical Communications, 2023 - pubs.rsc.org
… –lanthanide single-molecule magnets and multifunctional molecular magnetic materials. …
towards molecular magnetic materials including single-molecule magnets, cryogenic molecular …

Covalency and magnetic anisotropy in lanthanide single molecule magnets: the DyDOTA archetype

M Briganti, GF Garcia, J Jung, R Sessoli… - Chemical …, 2019 - pubs.rsc.org
… In the field of molecular magnetism the series of [Ln(DOTA)(H 2 O)] − was extensively
studied 3,4 as one of the pioneer complexes of lanthanide based Single Molecule Magnets (SMMs)…