Aerobic oxidative cleavage of vicinal diol fatty esters by a supported ruthenium hydroxide catalyst

…, P Blach, Y Raoul, C De Bellefon… - ACS Sustainable …, 2020 - ACS Publications
… by the oxidative cleavage with H 2 O 2 –HCOOH. (20) … catalyze the oxidative cleavage of
unsaturated fatty acids, but strong … be obtained by dihydroxylation of unsaturated fatty acid by H …

Oxidative cleavage of glycols derived from unsaturated fatty acids

A Vassoi - 2019 - amsdottorato.unibo.it
… of the dihydroxylation of the oleic acid contained in … cleavage of unsaturated fatty acids to
carboxylic acids, especially for the transformation of oleic acid to pelargonic and azelaic acids, …

Enzymatic regio-and enantioselective C–H oxyfunctionalization of fatty acids

H Chen, M Huang, W Yan, WJ Bai, X Wang - ACS Catalysis, 2021 - ACS Publications
… C18 saturated FAs as well as naturally derived unsaturated oleic … β-hydroxylation of fatty
acids. Herein, we report our findings. … Its successive reduction with SmI 2 cleaved the N–O bond …

Unexpected reactions of α, β‐unsaturated fatty acids provide insight into the mechanisms of CYP152 peroxygenases

Y Jiang, W Peng, Z Li, C You, Y Zhao… - Angewandte Chemie …, 2021 - Wiley Online Library
… of the unexpected CC bond cleavage products of fatty acid … the sequential C α -hydroxylation,
isomerization to α-keto fatty acid, and … enzymatic system for future practical applications. …

[HTML][HTML] Understanding desaturation/hydroxylation activity of castor stearoyl Δ9-Desaturase through rational mutagenesis

M Tupec, M Culka, A Machara, S Macháček… - Computational and …, 2022 - Elsevier
… Here, our aim is to exploit the practical consequences of the … -histidine tag and a thrombin
cleavage site. Q5 high-fidelity … mM CoA, and 2.5 mM fatty acid (oleic acid: 14.1 mg, 50 µmol; …

[HTML][HTML] Bioenzymatic and chemical derivatization of renewable fatty acids

RK Akula, YU Kwon - Biomolecules, 2019 - mdpi.com
… ; dihydroxylation can give diols and oxidative cleavage reactions can provide smaller (nine
carbon atoms) fatty acid … -friendly, cost-effective, and practical approaches to the large-scale …

[HTML][HTML] From tandem to catalysis–organic solvent nanofiltration for catalyst separation in the homogeneously W-catalyzed oxidative cleavage of renewable methyl 9 …

…, M Peters, A Schnettger, C Sichelschmidt… - Catalysis Science & …, 2022 - pubs.rsc.org
… bond cleavage of unsaturated fatty acids and fatty acid methyl esters… step of dihydroxylation
is followed by oxidative cleavage of … To create realistic reaction conditions but still exclude an …

Integral membrane fatty acid desaturases: a review of biochemical, structural, and biotechnological advances

M Nachtschatt, S Okada… - European Journal of Lipid …, 2020 - Wiley Online Library
… as acetylenation, conjugation, hydroxylation, and epoxidation. Here, … Practical Application:
Integral membrane fatty acid … substrate C10─H bond cleavage leading to desaturation in the …

[HTML][HTML] Biosynthesis of alkanes/alkenes from fatty acids or derivatives (triacylglycerols or fatty aldehydes)

RRC Monteiro, SSO da Silva, CL Cavalcante Jr… - Biotechnology …, 2022 - Elsevier
… of fatty acids (or derivatives) into hydrocarbons to be used as biofuels (biogasoline, green
diesel and jet biofuel). Among the used enzymes, the fatty acid … of free fatty acids and/or …

Recent advances in sustainable production and catalytic transformations of fatty acid methyl esters

AS Belousov, AL Esipovich, EA Kanakov… - Sustainable Energy & …, 2021 - pubs.rsc.org
… of oxidative cleavage of FAMEs and unsaturated fatty acids (… The reaction mechanism
involves the cis-dihydroxylation of … and these complexes are unlikely to find practical application. …