New applications of copper-catalyzed reversible-deactivation radical polymerization

S Gupta - 2024 - dspace.cuni.cz
… while for polymerizations utilizing metallic copper the term Cu… controlled polymerization of
styrene at 130 C in the presence … initiation sites, a copper catalyst can activate more than one …

Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications

N Corrigan, K Jung, G Moad, CJ Hawker… - Progress in Polymer …, 2020 - Elsevier
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (… (RAFT) polymerization and nitroxide mediated polymerization (NMP) …

The role of 2‐iminopyrrolyl copper (I) complexes in the ReversibleDeactivation Radical Polymerization of methyl methacrylate

HT de Matos, TFC Cruz… - Applied …, 2023 - Wiley Online Library
Copper has been the most used metal to mediate RDRP … In this latter case, the copper
complexes not only activate the … the highest polymerization rate, justified by the presence of the …

Progress toward sustainable reversible deactivation radical polymerization

PBV Scholten, D Moatsou… - Macromolecular …, 2020 - Wiley Online Library
… produced by reacting metallic copper and chlorine gas at … Bipy is obtained by dimerizing
pyridine in the presence of a … to report the RDRP of non-activated allylic double bonds, which …

Oxygen tolerant copper-mediated reversible deactivation radical polymerization

E Liarou - 2020 - wrap.warwick.ac.uk
… either via the reversible deactivation of the propagating radical to form the dormant species,
or via “degenerate transfer” between the propagating radicals and the dormant species. …

Step-growth irreversible deactivation radical polymerization: synergistic developments with chain-growth reversible deactivation radical polymerization

M Kamigaito - Bulletin of the Chemical Society of Japan, 2024 - academic.oup.com
… generate radical species in the presence of transition metal … The reversible activation and
deactivation process regulates … and polymerized it by ATRC in the presence of a copper catalyst…

Scalable Routes to Acrylate and Methacrylate Block Copolymers via Copper-Mediated Reversible Deactivation Radical Polymerization

HM Deacon, RA Hutchinson - Industrial & Engineering Chemistry …, 2024 - ACS Publications
copper species in the copper tube via the activation–deactivation equilibrium depends on the
presence of alkyl halide, ligand, and copper … the feed to the copper tube reactor could lead …

[HTML][HTML] Abc-type triblock copolyacrylamides via copper-mediated reversible deactivation radical polymerization

FM Alsubaie, OY Alothman, H Fouad, AHI Mourad - Polymers, 2021 - mdpi.com
… (0)-mediated reversible deactivation radical polymerization (… The full disproportionation of
CuBr in the presence of Me 6 … During the polymerization processes and the activation and …

Degradable and recyclable polymers by reversible deactivation radical polymerization

MR Martinez, K Matyjaszewski - CCS Chemistry, 2022 - chinesechemsoc.org
metal complex in an atom transfer radical polymerization (ATRP… is significantly reduced in
the presence of a large amount of … radical coupling between activated chain ends and TEMPO …

Can we push rapid reversible deactivation radical polymerizations toward immortality?

N Ballard, JM Asua - ACS Macro Letters, 2020 - ACS Publications
… the score and the social media presence for the given article. … of reversible deactivation
radical polymerization (RDRP) … over the nature of the activating species in some copper(0)-…