[图书][B] New Directions for the Multifunctional Catalytic Globin Dehaloperoxidase: Moving Beyond the Limits of the Structure-Function Paradigm of Heme Proteins
T Malewschik - 2021 - search.proquest.com
… to describe the gratitude and unconditional love I feel for all of … catalyzed by mono- and
dioxygenase enzymes A) hydroperoxo functionalization of polyunsaturated fatty acids catalyzed …
dioxygenase enzymes A) hydroperoxo functionalization of polyunsaturated fatty acids catalyzed …
Rejigging Electron and Proton Transfer to Transition between Dioxygenase, Monooxygenase, Peroxygenase, and Oxygen Reduction Activity: Insights from …
M Mukherjee, A Dey - JACS Au, 2021 - ACS Publications
… Nature has employed heme proteins to execute a diverse set … Naturally occurring
metalloenzymes catalyze crucial … enzymes can take part in oxygenation reaction, ie, incorporation …
metalloenzymes catalyze crucial … enzymes can take part in oxygenation reaction, ie, incorporation …
Cytochrome P450. The dioxygen-activating heme thiolate
FMC Martínez, DP López, PDS Pavía… - … A Strong Relationship …, 2020 - degruyter.com
… that only thiolate-ligated heme proteins can activate inert C–… functionally related enzymes,
chloroperoxidase (CPO) and … of cytochrome P450 catalyzed hydroxylation of saturated …
chloroperoxidase (CPO) and … of cytochrome P450 catalyzed hydroxylation of saturated …
Electron transfer control of reductase versus monooxygenase: Catalytic C–H bond hydroxylation and alkene epoxidation by molecular oxygen
M Mukherjee, A Dey - ACS Central Science, 2019 - ACS Publications
… slow and all the compound I produced catalyzes mono-oxygenation (a 2e- oxidation), one …
styrene oxidation reflect the relative rates of mono-oxygenation and ET in both cases. The FY …
styrene oxidation reflect the relative rates of mono-oxygenation and ET in both cases. The FY …
[HTML][HTML] Electrochemical transformations catalyzed by cytochrome P450s and peroxidases
… Thus, microsomal heme proteins catalyzed the oxygen … The enzyme can catalyze the
oxygenation of alkenes (non-… to bromolactone was catalyzed by vanadium chloroperoxidase with …
oxygenation of alkenes (non-… to bromolactone was catalyzed by vanadium chloroperoxidase with …
[HTML][HTML] Structural characterization of two short unspecific peroxygenases: two different dimeric arrangements
D Linde, E Santillana, E Fernández-Fueyo… - Antioxidants, 2022 - mdpi.com
… Unspecific peroxygenases (UPOs) are enzymes catalyzing the … peroxygenases, catalyze
selective oxygenation reactions with … Moreover, for many years, the related chloroperoxidase of …
selective oxygenation reactions with … Moreover, for many years, the related chloroperoxidase of …
[HTML][HTML] Common Reactivity and Properties of Heme Peroxidases: A DFT Study of Their Origin
… I, and compound II during catalysis (Scheme 1). Differences are … observed for compound II
of chloroperoxidase (CPO, a heme … the resting state of several heme proteins according to the …
of chloroperoxidase (CPO, a heme … the resting state of several heme proteins according to the …
Catalytic C–H bond oxidation using dioxygen by analogues of heme superoxide
M Mukherjee, A Dey - Inorganic Chemistry, 2020 - ACS Publications
… Iron porphyrins having different axial ligands are constructed on a self-assembled monolayer
of thiols on an electrode, and these constructs can activate O 2 and efficiently catalyze the …
of thiols on an electrode, and these constructs can activate O 2 and efficiently catalyze the …
Heme-FeIII Superoxide, Peroxide and Hydroperoxide Thermodynamic Relationships: FeIII-O2•– Complex H-Atom Abstraction Reactivity
Establishing redox and thermodynamic relationships between metal-ion-bound O 2 and its …
the thermodynamic square scheme and Bordwell relationship. This calculated O–H BDFE of …
the thermodynamic square scheme and Bordwell relationship. This calculated O–H BDFE of …
Inspiration from Nature: influence of engineered ligand scaffolds and auxiliary factors on the reactivity of biomimetic oxidants
… Thus, Cpd I is, therefore, responsible for a variety of oxygenation reactions such as C–H
activation, aromatic ring hydroxylation, olefin epoxidation, heteroatom oxidation, N-dealkylation, …
activation, aromatic ring hydroxylation, olefin epoxidation, heteroatom oxidation, N-dealkylation, …