Reductive transformation of birnessite and the mobility of co-associated antimony

N Karimian, SG Johnston, ED Burton - Journal of Hazardous Materials, 2021 - Elsevier
Manganese (Mn) oxide minerals, such as birnessite, are thought to play an important role in
affecting the mobility and fate of antimony (Sb) in the environment. In this study, we …

Antimonate controls manganese (II)-induced transformation of birnessite at a circumneutral pH

N Karimian, K Hockmann… - Environmental …, 2021 - ACS Publications
Manganese (Mn) oxides, such as birnessite (δ-MnO2), are ubiquitous mineral phases in
soils and sediments that can interact strongly with antimony (Sb). The reaction between …

Antimony oxidation and sorption behavior on birnessites with different properties (δ-MnO2 and triclinic birnessite)

Q Sun, PX Cui, C Liu, SM Peng, ME Alves… - Environmental …, 2019 - Elsevier
Birnessites are abundant naturally occurring minerals with high sorption and oxidation
capacity that could therefore play an important role in antimony (Sb) migration and …

Impacts of aqueous Mn (II) on the sorption of Zn (II) by hexagonal birnessite

JP Lefkowitz, EJ Elzinga - Environmental science & technology, 2015 - ACS Publications
We used a combination of batch studies and spectroscopic analyses to assess the impacts
of aqueous Mn (II) on the solubility and speciation of Zn (II) in anoxic suspensions of …

Influence of pH on the reductive transformation of birnessite by aqueous Mn (II)

JP Lefkowitz, AA Rouff, EJ Elzinga - Environmental science & …, 2013 - ACS Publications
We investigated the effect of pH (5.5–8.5) on the mineralogical transformation of hexagonal
birnessite induced by reaction with aqueous Mn (II)(50–2200 μM), using batch sorption …

Effect of Zn (II) coprecipitation on Mn (II)-induced reductive transformation of birnessite

S Zhao, YA González-Valle, EJ Elzinga, EM Saad… - Chemical …, 2018 - Elsevier
Mn oxides (MnOx) are ubiquitous metal oxide minerals in nearly all environmental settings.
They play important roles in the transport and fate of many environmental components such …

Mechanism of birnessite-promoted oxidative dissolution of antimony trioxide

J Shan, X Ding, M He, W Ouyang, C Lin… - Environmental …, 2020 - CSIRO Publishing
Environmental context The release of antimony and its compounds to the environment can
present a toxic hazard for humans. We evaluated the use of birnessite to dissolve antimony …

Enhanced removal of antimony by acid birnessite with doped iron ions: Companied by the structural transformation

H Lu, W Zhang, L Tao, F Liu, J Zhang - Chemosphere, 2019 - Elsevier
In the environment, antimony as a priority control pollutant is mainly associated with Fe-or
Mn-related minerals. In this work, acid birnessite (AB) doped with iron was synthesized as …

A review on the transformation of birnessite in the environment: Implication for the stabilization of heavy metals

M Shi, Q Li, Q Wang, X Yan, B Li, L Feng, C Wu… - Journal of …, 2023 - Elsevier
Birnessite is ubiquitous in the natural environment where heavy metals are retained and
easily transformed. The surface properties and structure of birnessite change with the …

Structural transformation of birnessite by fulvic acid under anoxic conditions

Q Wang, P Yang, M Zhu - Environmental science & technology, 2018 - ACS Publications
The structure and Mn (III) concentration of birnessite dictate its reactivity and can be
changed by birnessite partial reduction, but effects of pH and reductant/birnessite ratios on …