Coupled effects of Mn (II), pH and anionic ligands on the reactivity of nanostructured birnessite

Q Li, R Pokharel, L Zhou, M Pasturel… - Environmental Science …, 2020 - pubs.rsc.org
While the oxidative capacity of nanostructured birnessite-type manganese oxide has been
widely investigated, no comprehensive work exists on the combined effects of dissolved Mn …

Characterization of Ni-rich hexagonal birnessite and its geochemical effects on aqueous Pb2+/Zn2+ and As (III)

H Yin, W Tan, L Zheng, H Cui, G Qiu, F Liu… - … et cosmochimica acta, 2012 - Elsevier
Hexagonal birnessite is the most ubiquitous manganese oxide in geological environments. It
is often highly enriched in trace metal ions such as Ni and plays an important role in metal …

Role of bacterial biomass in the sorption of Ni by biomass-birnessite assemblages

J Peña, JR Bargar, G Sposito - Environmental science & …, 2011 - ACS Publications
Birnessites precipitated by bacteria are typically poorly crystalline Mn (IV) oxides enmeshed
within biofilms to form complex biomass–birnessite assemblages. The strong sorption affinity …

Sorption of antimony (V) to naturally formed multicomponent secondary iron minerals: Sorption behavior and a comparison with synthetic analogs

L Peng, H Li, W Lin, T Xiao, J Wang, J Tang… - Science of The Total …, 2024 - Elsevier
Antimony (Sb) pollution in water has attracted extensive attention due to the biotoxicity of Sb.
Secondary iron minerals readily sorb heavy metal (loid) s and critically affect their cycling in …

XPS study of dissolution of birnessite by humate with constraints on reaction mechanism

D Banerjee, HW Nesbitt - Geochimica et Cosmochimica Acta, 2001 - Elsevier
The present study is an investigation into the surface reactions of synthetic birnessite [Mn (II)
0.05 Mn (III) 0.25 Mn (IV) 0.7 O1. 7 (OH) 0.25] when reacted with dilute (5× 10− 4 M) Na …

Immobilization mechanism of antimony by applying zirconium‐manganese oxide in soil

Q Rong, X Nong, C Zhang, K Zhong, H Zhao - Science of the Total …, 2022 - Elsevier
Antimony (Sb) accumulation in soil poses great potential risk to ecological environment, and
its mobilization, transformation and bioavailability are controlled by its fractions and species …

Coordination geometry of Zn2+ on hexagonal turbostratic birnessites with different Mn average oxidation states and its stability under acid dissolution

H Yin, X Wang, Z Qin, M Ginder-Vogel, S Zhang… - Journal of …, 2018 - Elsevier
Hexagonal turbostratic birnessite, with the characteristics of high contents of vacancies,
varying amounts of structural and adsorbed Mn 3+, and small particle size, undergoes …

Behavior of antimony (V) during the transformation of ferrihydrite and its environmental implications

S Mitsunobu, C Muramatsu, K Watanabe… - … Science & Technology, 2013 - ACS Publications
In this study, we investigated the behavior of Sb (V) during the transformation of poorly
crystalline Fe (III) oxyhydroxides (two-line ferrihydrite) with various Sb/Fe molar ratios at pH …

A microscopic and spectroscopic study of rapid antimonite sequestration by a poorly crystalline phyllomanganate: differences from passivated arsenite oxidation

H Wang, Y Wang, Y Sun, YF Tsang, D Zhang, X Pan - RSC advances, 2017 - pubs.rsc.org
During the reaction of arsenite (As (III)) with δ-MnO2 (a typically poorly crystalline
phyllomanganate), a significant decrease in the oxidation rate is frequently observed, which …

Transformations of synthetic birnessite as affected by pH and manganese concentration

S Tu, GJ Racz, TB Goh - Clays and Clay Minerals, 1994 - cambridge.org
The amount of Mn2+ adsorbed or removed from solution by birnessite is several times
greater than its reported cation exchange capacity. Extractability of the sorbed Mn2+ …