Understanding TADF: a joint experimental and theoretical study of DMAC-TRZ

R Dhali, DKAP Huu, F Bertocchi, C Sissa… - Physical Chemistry …, 2021 - pubs.rsc.org
Thermally-activated delayed fluorescence (TADF) is a promising strategy to harvest triplets
in OLED towards improved efficiency, but several issues must be addressed to fully exploit …

Understanding the fluorescence of TADF light-emitting dyes

G Valchanov, A Ivanova, A Tadjer… - The Journal of …, 2016 - ACS Publications
In order to afford in a controlled fashion fine-tuning of the color and the intensity of the
emitted light of potential fluorophores for organic light-emitting diodes (OLED), directed …

[HTML][HTML] Thermally activated delayed fluorescence: A critical assessment of environmental effects on the singlet–triplet energy gap

R Dhali, DK Phan Huu, F Terenziani, C Sissa… - The Journal of …, 2021 - pubs.aip.org
The effective design of dyes optimized for thermally activated delayed fluorescence (TADF)
requires the precise control of two tiny energies: the singlet–triplet gap, which has to be …

Modeling TADF in organic emitters requires a careful consideration of the environment and going beyond the Franck–Condon approximation

JM Mewes - Physical Chemistry Chemical Physics, 2018 - pubs.rsc.org
The origin of the thermally-activated delayed fluorescence (TADF) of three organic emitters
is investigated, focusing on the nature of the lowest excited states, their transition properties …

Thermally activated delayed fluorescence (TADF) path toward efficient electroluminescence in purely organic materials: molecular level insight

XK Chen, D Kim, JL Brédas - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus Since the seminal work of Tang and Vanslyke in 1987 on small-molecule
emitters and that of Friend and co-workers in 1990 on conjugated-polymer emitters, organic …

Photophysics of thermally activated delayed fluorescence molecules

FB Dias, TJ Penfold, AP Monkman - Methods and applications in …, 2017 - iopscience.iop.org
Thermally activated delayed fluorescence (TADF) has recently emerged as one of the most
attractive methods for harvesting triplet states in metal-free organic materials for application …

Revealing the spin–vibronic coupling mechanism of thermally activated delayed fluorescence

MK Etherington, J Gibson, HF Higginbotham… - Nature …, 2016 - nature.com
Knowing the underlying photophysics of thermally activated delayed fluorescence (TADF)
allows proper design of high efficiency organic light-emitting diodes. We have proposed a …

Charge transfer as the key parameter affecting the color purity of thermally activated delayed fluorescence emitters

R Ansari, W Shao, SJ Yoon, J Kim… - ACS Applied Materials & …, 2021 - ACS Publications
The key factors determining the emission bandwidth of thermally activated delayed
fluorescence (TADF) are investigated by combining computational and experimental …

Thermally activated delayed fluorescence materials: towards realization of high efficiency through strategic small molecular design

X Liang, ZL Tu, YX Zheng - Chemistry–A European Journal, 2019 - Wiley Online Library
Thermally activated delayed fluorescence (TADF) is one of the most intriguing and
promising discoveries towards realization of highly‐efficient organic light emitting diodes …

Unexpected quasi‐axial conformer in thermally activated delayed fluorescence DMAC‐TRZ, pushing green OLEDs to blue

K Stavrou, LG Franca, T Böhmer… - Advanced Functional …, 2023 - Wiley Online Library
Hidden photophysics is elucidated in the very well‐known thermally activated delayed
fluorescence (TADF) emitter, DMAC‐TRZ. A molecule that, based on its structure, is …