Effect of Zn (II) coprecipitation on Mn (II)-induced reductive transformation of birnessite

S Zhao, YA González-Valle, EJ Elzinga, EM Saad… - Chemical …, 2018 - Elsevier
Mn oxides (MnOx) are ubiquitous metal oxide minerals in nearly all environmental settings.
They play important roles in the transport and fate of many environmental components such …

Effects of metal cations on coupled birnessite structural transformation and natural organic matter adsorption and oxidation

Q Wang, P Yang, M Zhu - Geochimica et Cosmochimica Acta, 2019 - Elsevier
Birnessite, a layered manganese (Mn) oxide, possesses extraordinary metal adsorption and
oxidation activity, and thus imposes impacts on many biogeochemical processes. The …

Influence of pH on the reductive transformation of birnessite by aqueous Mn (II)

JP Lefkowitz, AA Rouff, EJ Elzinga - Environmental science & …, 2013 - ACS Publications
We investigated the effect of pH (5.5–8.5) on the mineralogical transformation of hexagonal
birnessite induced by reaction with aqueous Mn (II)(50–2200 μM), using batch sorption …

Antimonate controls manganese (II)-induced transformation of birnessite at a circumneutral pH

N Karimian, K Hockmann… - Environmental …, 2021 - ACS Publications
Manganese (Mn) oxides, such as birnessite (δ-MnO2), are ubiquitous mineral phases in
soils and sediments that can interact strongly with antimony (Sb). The reaction between …

Inhibition of oxyanions on redox-driven transformation of layered manganese oxides

P Yang, K Wen, KA Beyer, W Xu, Q Wang… - Environmental …, 2021 - ACS Publications
Layered manganese (Mn) oxides, such as birnessite, can reductively transform into other
phases and thereby affect the environmental behavior of Mn oxides. Solution chemistry …

Effect of Zn coprecipitation on the structure of layered Mn oxides

S Zhao, Q Wang, J Sun, OJ Borkiewicz, R Huang… - Chemical …, 2018 - Elsevier
Mn oxides (MnO x) are a group of ubiquitous metal oxides in the environment and can
significantly affect the biogeochemical cycles of metals, nutrients, and contaminants. Due to …

Reductive transformation of birnessite by aqueous Mn (II)

EJ Elzinga - Environmental science & technology, 2011 - ACS Publications
Reaction of aqueous Mn (II) with hexagonal birnessite at pH 7.5 causes reductive
transformation of birnessite into feitknechtite (β-MnIIIOOH) and manganite (γ-MnIIIOOH) …

Effects of Co and Ni co-doping on the structure and reactivity of hexagonal birnessite

H Yin, H Li, Y Wang, M Ginder-Vogel, G Qiu, X Feng… - Chemical …, 2014 - Elsevier
Natural hexagonal birnessites are enriched in various transition metals (TMs). Many studies
have examined the effects of single metal doping on the structures and properties of …

[HTML][HTML] Tunable Mn oxidation state and redox potential of birnessite coexisting with aqueous Mn (II) in mildly acidic environments

J Liu, Y Zhang, Q Gu, A Sheng, B Zhang - Minerals, 2020 - mdpi.com
As the dominant manganese oxide mineral phase in terrestrial and aquatic environments,
birnessite plays an important role in many biogeochemical processes. The coexistence of …

Structural transformation of birnessite by fulvic acid under anoxic conditions

Q Wang, P Yang, M Zhu - Environmental science & technology, 2018 - ACS Publications
The structure and Mn (III) concentration of birnessite dictate its reactivity and can be
changed by birnessite partial reduction, but effects of pH and reductant/birnessite ratios on …