Effect of Zn (II) coprecipitation on Mn (II)-induced reductive transformation of birnessite
S Zhao, YA González-Valle, EJ Elzinga, EM Saad… - Chemical …, 2018 - Elsevier
Mn oxides (MnOx) are ubiquitous metal oxide minerals in nearly all environmental settings.
They play important roles in the transport and fate of many environmental components such …
They play important roles in the transport and fate of many environmental components such …
Effects of metal cations on coupled birnessite structural transformation and natural organic matter adsorption and oxidation
Birnessite, a layered manganese (Mn) oxide, possesses extraordinary metal adsorption and
oxidation activity, and thus imposes impacts on many biogeochemical processes. The …
oxidation activity, and thus imposes impacts on many biogeochemical processes. The …
Influence of pH on the reductive transformation of birnessite by aqueous Mn (II)
JP Lefkowitz, AA Rouff, EJ Elzinga - Environmental science & …, 2013 - ACS Publications
We investigated the effect of pH (5.5–8.5) on the mineralogical transformation of hexagonal
birnessite induced by reaction with aqueous Mn (II)(50–2200 μM), using batch sorption …
birnessite induced by reaction with aqueous Mn (II)(50–2200 μM), using batch sorption …
Antimonate controls manganese (II)-induced transformation of birnessite at a circumneutral pH
N Karimian, K Hockmann… - Environmental …, 2021 - ACS Publications
Manganese (Mn) oxides, such as birnessite (δ-MnO2), are ubiquitous mineral phases in
soils and sediments that can interact strongly with antimony (Sb). The reaction between …
soils and sediments that can interact strongly with antimony (Sb). The reaction between …
Inhibition of oxyanions on redox-driven transformation of layered manganese oxides
Layered manganese (Mn) oxides, such as birnessite, can reductively transform into other
phases and thereby affect the environmental behavior of Mn oxides. Solution chemistry …
phases and thereby affect the environmental behavior of Mn oxides. Solution chemistry …
Effect of Zn coprecipitation on the structure of layered Mn oxides
Mn oxides (MnO x) are a group of ubiquitous metal oxides in the environment and can
significantly affect the biogeochemical cycles of metals, nutrients, and contaminants. Due to …
significantly affect the biogeochemical cycles of metals, nutrients, and contaminants. Due to …
Reductive transformation of birnessite by aqueous Mn (II)
EJ Elzinga - Environmental science & technology, 2011 - ACS Publications
Reaction of aqueous Mn (II) with hexagonal birnessite at pH 7.5 causes reductive
transformation of birnessite into feitknechtite (β-MnIIIOOH) and manganite (γ-MnIIIOOH) …
transformation of birnessite into feitknechtite (β-MnIIIOOH) and manganite (γ-MnIIIOOH) …
Effects of Co and Ni co-doping on the structure and reactivity of hexagonal birnessite
Natural hexagonal birnessites are enriched in various transition metals (TMs). Many studies
have examined the effects of single metal doping on the structures and properties of …
have examined the effects of single metal doping on the structures and properties of …
[HTML][HTML] Tunable Mn oxidation state and redox potential of birnessite coexisting with aqueous Mn (II) in mildly acidic environments
As the dominant manganese oxide mineral phase in terrestrial and aquatic environments,
birnessite plays an important role in many biogeochemical processes. The coexistence of …
birnessite plays an important role in many biogeochemical processes. The coexistence of …
Structural transformation of birnessite by fulvic acid under anoxic conditions
The structure and Mn (III) concentration of birnessite dictate its reactivity and can be
changed by birnessite partial reduction, but effects of pH and reductant/birnessite ratios on …
changed by birnessite partial reduction, but effects of pH and reductant/birnessite ratios on …