Diffusion measurements of hydrocarbons in zeolites with pulse-field gradient nuclear magnetic resonance spectroscopy

VV Zhivonitko, Z Vajglová, P Mäki-Arvela… - Russian Journal of …, 2021 - Springer
Pulse field gradient NMR technique was used to determine self-diffusivity of heptane and
pentadecane at room temperature for microporous catalysts, used both as powders and …

Molecular mobility measurement of hydrocarbons in zeolites by NMR techniques

J Caro, M Bülow, H Jobic, J Kärger, B Zibrowius - Advances in catalysis, 1993 - Elsevier
Publisher Summary This chapter reviews the most relevant experimental methods to follow
molecular translations and/or reorientations of guest molecules in zeolite pores. The benefit …

Diffusion measurements of hydrocarbons in H-MCM-41 extrudates with pulsed-field gradient nuclear magnetic resonance spectroscopy

VV Zhivonitko, Z Vajglová, P Mäki-Arvela… - Physical Chemistry …, 2022 - pubs.rsc.org
Mesoporous materials are promising catalysts for production of biofuels. Herein, H-MCM-41
catalysts with different concentrations of the silica Bindzil binder (10–50 wt%) were prepared …

Long-range diffusion in beds of nanoporous particles: pitfalls and potentials

S Vasenkov, J Kärger - Magnetic resonance imaging, 2005 - Elsevier
Owing to the recent progress in the area of hardware and software of the pulsed field
gradient NMR technique, molecular transport in real-life zeolite systems, such as zeolite …

Multidimensional NMR diffusion studies in microporous materials

M Gratz, M Wehring, P Galvosas, F Stallmach - … and mesoporous materials, 2009 - Elsevier
The diffusional behavior of selected hydrocarbons adsorbed in NaX zeolites were
investigated with pulsed magnetic field gradient (PFG) NMR methods in two different ways …

[PDF][PDF] PFG NMR measurements of tortuosity factors for diffusion in meso-and macropores of FCC catalysts

S Vasenkov, P Kortunov - 2005 - academia.edu
Pulsed field gradient (PFG) NMR is applied to measure self-diffusion coefficients of 1, 3, 5
triisopropyl-benzene in the particles of several industrial FCC catalysts having different …

High-temperature pulsed field gradient nuclear magnetic resonance self-diffusion measurements of n-alkanes in MFl-type zeolites

W Heink, J Kärger, H Pfeifer, KP Datema… - Journal of the Chemical …, 1992 - pubs.rsc.org
The coefficients of intracrystalline self-diffusion of the n-alkanes from propane to n-alkanes
from propane to n-hexane adsorbed in zeolite ZSM-5 are studied by means of the pulsed …

In Situ13C Fourier Transform Pulsed Field Gradient NMR Study of Intracrystalline Diffusion during Isopropanol Conversion in X-Type Zeolites

HB Schwarz, S Ernst, J Kärger, B Knorr, G Seiffert… - Journal of …, 1997 - Elsevier
13C Fourier transform pulsed field gradient NMR was applied for the first time for thein
situobservation of the self-diffusion of reactant and product molecules during a zeolite …

Diffusion in Nanoporous Ma terials: from Paradigm Shift by Zhdanov Zeolites Till Recent Insight

J Kärger, D Freude, II Ivanova, AG Stepanov - Petroleum Chemistry, 2019 - Springer
Our present knowledge of the translational mobility of guest molecules in zeolites would be
unthinkable without the involvement of the giant zeolite crystallites synthesized by Prof …

PFG NMR self-diffusion of small hydrocarbons in high silica DDR, CHA and LTA structures

N Hedin, GJ DeMartin, WJ Roth, KG Strohmaier… - Microporous and …, 2008 - Elsevier
Pulsed field gradient (PFG) nuclear magnetic resonance (NMR) spectroscopy was used to
measure and rationalize the intracrystalline self-diffusion coefficients of small hydrocarbons …