Coupled effects of Mn (II), pH and anionic ligands on the reactivity of nanostructured birnessite

Q Li, R Pokharel, L Zhou, M Pasturel… - Environmental Science …, 2020 - pubs.rsc.org
While the oxidative capacity of nanostructured birnessite-type manganese oxide has been
widely investigated, no comprehensive work exists on the combined effects of dissolved Mn …

Characterization of Ni-rich hexagonal birnessite and its geochemical effects on aqueous Pb2+/Zn2+ and As (III)

H Yin, W Tan, L Zheng, H Cui, G Qiu, F Liu… - … et cosmochimica acta, 2012 - Elsevier
Hexagonal birnessite is the most ubiquitous manganese oxide in geological environments. It
is often highly enriched in trace metal ions such as Ni and plays an important role in metal …

Influence of pH on the reductive transformation of birnessite by aqueous Mn (II)

JP Lefkowitz, AA Rouff, EJ Elzinga - Environmental science & …, 2013 - ACS Publications
We investigated the effect of pH (5.5–8.5) on the mineralogical transformation of hexagonal
birnessite induced by reaction with aqueous Mn (II)(50–2200 μM), using batch sorption …

Characterization of Co-doped birnessites and application for removal of lead and arsenite

H Yin, X Feng, G Qiu, W Tan, F Liu - Journal of hazardous materials, 2011 - Elsevier
Nanostructured Co-doped birnessites were successfully synthesized, and their application
for the removal of Pb2+ and As (III) from aquatic systems was investigated. Powder X-ray …

Coordination geometry of Zn2+ on hexagonal turbostratic birnessites with different Mn average oxidation states and its stability under acid dissolution

H Yin, X Wang, Z Qin, M Ginder-Vogel, S Zhang… - Journal of …, 2018 - Elsevier
Hexagonal turbostratic birnessite, with the characteristics of high contents of vacancies,
varying amounts of structural and adsorbed Mn 3+, and small particle size, undergoes …

The influence of particle size and structure on the sorption and oxidation behavior of birnessite: I. Adsorption of As (V) and oxidation of As (III)

M Villalobos, IN Escobar-Quiroz… - … et Cosmochimica Acta, 2014 - Elsevier
Sorption and oxidation reactions in the environment may affect substantially the mobility of
redox-sensitive toxic trace elements and compounds. Investigating the environmental factors …

Transformation of hexagonal birnessite upon reaction with thallium (I): Effects of birnessite crystallinity, pH, and thallium concentration

M Ruiz-Garcia, M Villalobos, A Voegelin… - Environmental …, 2021 - ACS Publications
We examined the uptake of Tl (I) by two hexagonal birnessites and related phase
transformations in laboratory experiments over 12 sequential additions of 0.01 M Tl (I)/Mn at …

Synergetic effects of Mn (II) production and site availability on arsenite oxidation and arsenate adsorption on birnessite in the presence of low molecular weight …

M Liang, H Guo, W Xiu - Journal of Hazardous Materials, 2024 - Elsevier
Manganese oxides and organic acids are key factors affecting arsenic mobility, but As (III)
oxidation and adsorption in the coexistence of birnessite and low molecular weight organic …

Effects of low molecular weight organic acids with different functional groups on arsenate adsorption on birnessite

M Liang, H Guo, W Xiu - Journal of Hazardous Materials, 2022 - Elsevier
In an aquatic ecosystem, especially constructed wetlands receiving arsenic (As)-containing
wastewater, the fate and mobility of As is influenced by manganese (Mn) oxides and organic …

Arsenic (III) oxidation by birnessite and precipitation of manganese (II) arsenate

C Tournassat, L Charlet, D Bosbach… - … Science & Technology, 2002 - ACS Publications
Solution chemical techniques were used to investigate the oxidation of As (III) to As (V) in
0.011 M arsenite suspension of well-crystallized hexagonal birnessite (H-birnessite, 2.7 g L …