… aldehydes, the formation of aliphatic acyl radicals via alkyl aldehyde C(sp 2 )–H bond cleavage
… radicals generated by the oxidation of aliphatic aldehydes under heated conditions can …

… C–C bond cleavage involves 1,3-O/C migration and aerobic … 2 direct from benzylamines 4
and ynones 5 was adopted to … )-one products 2 were formed by the aerobic oxidation of 1,5-…

… C–C bond cleavage and a Kornblum-type oxidation of … 139 and α,β-unsaturated aldehydes
142 by a combination of the … In addition to ynones, ynamides 195a and ynoates 195b–c …

… carbaglucoses react by pseudoglycosidic bond cleavage via an SN1 process in … The aerobic
oxidation of benzylamine to N-… The 3 + 2 annulation of ynones and aminocrotonates gives …

… and the key to induce the consecutive CC bond cleavage. We also synthesized aldehyde
58a and 59a. When aldehyde 58a was reacted under standard condition, product 58b was …

… of the aldehyde and α-C of enamines, and oxidative … reaction of trifluoromethyl-α,β-ynones
with β-enamino esters or β-… In this aerobic oxidation reaction, using molecular oxygen as the …

… by regioselective insertion into the resulting ynone 37. Subsequently, 1,… 239 formed after
cleavage of the aldehyde group was … (0) species that is reoxidized under the aerobic conditions. …

… development of chemical synthesis. The selective C–C bond cleavage and functionalizations
… ) activations, LMCT promotes the substrate oxidation by directly exciting the LMCT band of …

… for the generation of acyl radicals via aerobic CH activation [43]… route for the efficient synthesis
of ynones from aldehydes. … , which triggered the NO bond cleavage to generate an amidyl …

… α,β-unsaturated aldehyde. According to their proposed … literature for the initial formation of
a ynone. A wide range of terminal … substrates to tertiary anilines via C–N bond cleavage. (67b) …