… The ability of the synthesized acrylic monomers to polymerize was checked in free radical
polymerizations carried out using AIBN as an initiator (monomer/AIBN = 516) during 2 h at 80 …

… (4) The bioinspired acyl radical cyclization/hemiketalization cascade is successfully applied
… Notably, the strategy is also amenable to the concise synthesis of terpenoid natural products…

… Based on the biosynthetic logic of terpenoid natural products, we introduced a bio-inspired
strategy for the chemical space exploration of terpenoids (Figure 1B), named TeroGen. In …

… -step synthesis of the cembrane diterpene chatancin from dihydrofarnesal using a bioinspired—…
We then show how a radical cyclization cascade can forge the hallmark cyclooctane ring …

… synthesis of hyperireflexolides A and B (Scheme 3). While we retained the bioinspired …
7, we planned its convergent synthesis by diastereoselective acylation and prenylation of …

… 6–7 terpene ring system fused to a benzofuran. We proposed a bioinspired cascade reaction
… of noncanonical PPAPs, such as the cage-like garcibracteatone (1), using oxidative radical …

… using prenyl migrations and subsequent epoxidation and radical cyclization to afford
numerous terpene frameworks relevant for natural product total synthesis. In these structures, the …

… our hands, we submitted it to bioinspired radical cyclization, catalyzed by titanocene(III),
which has been extensively studied and applied by us in natural terpene synthesis [5,12]. Under …

… initiated a program in the synthesis of biologically active polyketide/terpenoid hybrids (ie, …
advances in asymmetric synthesis, contemporary radical chemistry, and methods for inert bond …

… synthesis logic that has been applied to terpenes is also a powerful strategy for steroid
synthesis… alkoxy radical intermediate B, which undergoes β-fragmentation to furnish C10-alkyl …