Organolanthanide Single‐Molecule Magnets with Heterocyclic Ligands
Y Wang, QC Luo, YZ Zheng - … Chemie International Edition, 2024 - Wiley Online Library
… ligands was then well-demonstrated by the cyclopentadienyl (Cp) based Dy(III)SMM.[24] For
such SMMs the distance from the ring … [24] Represented by the Cp based ligands lanthanide …
such SMMs the distance from the ring … [24] Represented by the Cp based ligands lanthanide …
Metal–metal bond in lanthanide single-molecule magnets
Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
… valence orbitals, eg (n + 1)s, (n + 1)p, and nd orbitals, for the efficient orbital overlap, and
sterically encumbered ligands to preclude the coordination of other ligands to the metal centre. …
sterically encumbered ligands to preclude the coordination of other ligands to the metal centre. …
Understanding Single-Molecule Magnet properties of lanthanide complexes from 4f orbital splitting
Y Gil, D Aravena - Dalton Transactions, 2024 - pubs.rsc.org
… for cyclopentadienyl Dy III complexes in comparison with other ligands based on organometallic
rings), … tool to expand our description of ligand field effects in lanthanide-based SMMs. …
rings), … tool to expand our description of ligand field effects in lanthanide-based SMMs. …
Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets
… lanthanide single-molecule magnets (SMMs) have progressively evolved in recent years.
Lanthanide … and symmetry of the ligand field environment about the magnetic metal centre as …
Lanthanide … and symmetry of the ligand field environment about the magnetic metal centre as …
Get under the Umbrella: A Comprehensive Gateway for Researchers on Lanthanide‐Based Single‐Molecule Magnets
K Bernot - European Journal of Inorganic Chemistry, 2023 - Wiley Online Library
… known as an "umbrella review" on lanthanide-based single-molecule magnets (4f-SMM). As
a … A particular focus in pointed toward ligands adapted to divalent and tetravalent lanthanide …
a … A particular focus in pointed toward ligands adapted to divalent and tetravalent lanthanide …
Cyclopentadienyl-based lanthanoid complexes exhibiting magnetic and luminescence properties
E Barkas - 2021 - jyx.jyu.fi
… For instance, aryl-substituted cyclopentadienyl ligands have … of lanthanoid-based
single-molecule magnets.The main … that can function as single-molecule magnets. Trivalent …
single-molecule magnets.The main … that can function as single-molecule magnets. Trivalent …
Single Molecule Magnets
M Giansiracusa, G Gransbury… - … of Inorganic and …, 2021 - research.manchester.ac.uk
… literature blocking temperatures it was speculative whether such a complex would enable
higher blocking temperatures. One synthetic direction was to design bulky ligands to support a …
higher blocking temperatures. One synthetic direction was to design bulky ligands to support a …
Development and Prospects in the Structure and Performance of Lanthanide Single-Molecule Magnets
J Li, Y Yang, Q Yu, G Su, W Liu - The Journal of Physical …, 2024 - ACS Publications
… cyclopentadiene-based rare earth monomolecular magnets. … bridge-linked rare earth
single-molecule magnet system. By … -linked ligand, they successfully achieved robust magnetic …
single-molecule magnet system. By … -linked ligand, they successfully achieved robust magnetic …
Pyrrolyl-Bridged Metallocene Complexes: From Synthesis, Electronic Structure, to Single-Molecule Magnetism
F Delano IV, F Benner, S Jang, S Demir - Inorganic Chemistry, 2023 - ACS Publications
… Pyrrolyl ligands are isoelectronic with cyclopentadienyl rings … single-molecule magnets with
two bridging anionic ligands in … a rare lanthanide-based SMM containing pyrrolyl ligands in …
two bridging anionic ligands in … a rare lanthanide-based SMM containing pyrrolyl ligands in …
[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time
A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
… of everything, but it went through highly anisotropic low coordinate 3d compounds, lanthanide
based magnets… is worth mentioning that in some cases azide was used as auxiliary ligand …
based magnets… is worth mentioning that in some cases azide was used as auxiliary ligand …