Single molecule investigation of nanoconfinement hydrophobicity in heterogeneous catalysis

B Dong, N Mansour, Y Pei, Z Wang… - Journal of the …, 2020 - ACS Publications
… physical constraints of nanoconfinement on molecular orientation and enrichment of reaction
intermediates. (20) In the present work, we report new efforts on understanding the critical …

Orientation Bias of Self-Assembled Alkanes and Their Derivatives Under Dynamic Lateral Nanoconfinement Conditions

L Yu, Y Xia, T Hu, B Daelemans, S De Feyter - CCS Chemistry, 2024 - chinesechemsoc.org
… light on how nanoconfinement impacts and potentially alleviates … molecule assembly along
the fast shaving direction. Overall, this study provides insights into interpreting the molecular

Profiling single-molecule reaction kinetics under nanopore confinement

W Liu, ZL Yang, CN Yang, YL Ying, YT Long - Chemical Science, 2022 - pubs.rsc.org
… -molecule reaction under nanoconfinement is beneficial for understanding the reactive
intermediates and reaction … However, the kinetics model of the single-molecule reaction under …

Chemical reactivity under nanoconfinement

AB Grommet, M Feller, R Klajn - Nature nanotechnology, 2020 - nature.com
understanding of the conditions required for life to begin 9 . For the purpose of this Review,
nanoconfinement is … to bind entire molecules or reactive intermediates, partial confinement …

Unravelling the fundamental insights underlying “confinement effects” in enhanced electrocatalysis

J Zhou, M Zhang, L Yamei, X Jing, C Pan, L Yang… - Nano Energy, 2024 - Elsevier
understanding of how and why “confinement effectsimpact … that the unique characteristics
of nanoconfined water could … of related reaction intermediates, the “confinement effects” can …

Single molecule fluorescence imaging of nanoconfinement in porous materials

B Dong, N Mansour, TX Huang, W Huang… - Chemical Society …, 2021 - pubs.rsc.org
molecule fluorescence imaging in understanding the effects … that the confined molecular
orientation was the reason for the … Enrichment of the reaction intermediate enhances the overall …

Making and breaking of chemical bonds in single nanoconfined molecules

O Bunjes, D Hedman, A Rittmeier, LA Paul… - Science …, 2022 - science.org
… to the understanding of single-molecule reactions that are of … Nonetheless, though may be
necessary as intermediate, we … of the corresponding molecule orientation. This procedure was …

Nanoconfinement-Dependent Chain Orientation of Polymorphs in Poly (3-dodecylthiophene) s

H Park, H Park, H Ahn, W Lee, J Park, BJ Kim… - Chemistry of …, 2023 - ACS Publications
… intermolecular assembly and molecular orientation is essential for … The chain orientations of
Form I and Form II crystals in … a fundamental understanding of the nanoconfinement effect on …

Making more with less: confinement effects for more sustainable chemical transformations

JCS Terra, AR Martins, FCC Moura, CC Weber… - Green …, 2022 - pubs.rsc.org
… is central to understanding effects from the molecular to … to observe single molecules and
study nanoconfined dynamic … a preferred molecular orientation but the random molecular

Nanoconfinement raises the energy barrier to hydrogen atom exchange between water and glucose

SL Miller, BP Wiebenga-Sanford… - The Journal of …, 2021 - ACS Publications
… a model to increase understanding of a wide … of nanoconfinement could be used to introduce
energy barriers that allow for the study of previously unobserved high energy intermediates