Single molecule investigation of nanoconfinement hydrophobicity in heterogeneous catalysis
… physical constraints of nanoconfinement on molecular orientation and enrichment of reaction
intermediates. (20) In the present work, we report new efforts on understanding the critical …
intermediates. (20) In the present work, we report new efforts on understanding the critical …
Orientation Bias of Self-Assembled Alkanes and Their Derivatives Under Dynamic Lateral Nanoconfinement Conditions
… light on how nanoconfinement impacts and potentially alleviates … molecule assembly along
the fast shaving direction. Overall, this study provides insights into interpreting the molecular …
the fast shaving direction. Overall, this study provides insights into interpreting the molecular …
Profiling single-molecule reaction kinetics under nanopore confinement
… -molecule reaction under nanoconfinement is beneficial for understanding the reactive
intermediates and reaction … However, the kinetics model of the single-molecule reaction under …
intermediates and reaction … However, the kinetics model of the single-molecule reaction under …
Chemical reactivity under nanoconfinement
AB Grommet, M Feller, R Klajn - Nature nanotechnology, 2020 - nature.com
… understanding of the conditions required for life to begin 9 . For the purpose of this Review,
nanoconfinement is … to bind entire molecules or reactive intermediates, partial confinement …
nanoconfinement is … to bind entire molecules or reactive intermediates, partial confinement …
Unravelling the fundamental insights underlying “confinement effects” in enhanced electrocatalysis
J Zhou, M Zhang, L Yamei, X Jing, C Pan, L Yang… - Nano Energy, 2024 - Elsevier
… understanding of how and why “confinement effects” impact … that the unique characteristics
of nanoconfined water could … of related reaction intermediates, the “confinement effects” can …
of nanoconfined water could … of related reaction intermediates, the “confinement effects” can …
Single molecule fluorescence imaging of nanoconfinement in porous materials
… molecule fluorescence imaging in understanding the effects … that the confined molecular
orientation was the reason for the … Enrichment of the reaction intermediate enhances the overall …
orientation was the reason for the … Enrichment of the reaction intermediate enhances the overall …
Making and breaking of chemical bonds in single nanoconfined molecules
O Bunjes, D Hedman, A Rittmeier, LA Paul… - Science …, 2022 - science.org
… to the understanding of single-molecule reactions that are of … Nonetheless, though may be
necessary as intermediate, we … of the corresponding molecule orientation. This procedure was …
necessary as intermediate, we … of the corresponding molecule orientation. This procedure was …
Nanoconfinement-Dependent Chain Orientation of Polymorphs in Poly (3-dodecylthiophene) s
… intermolecular assembly and molecular orientation is essential for … The chain orientations of
Form I and Form II crystals in … a fundamental understanding of the nanoconfinement effect on …
Form I and Form II crystals in … a fundamental understanding of the nanoconfinement effect on …
Making more with less: confinement effects for more sustainable chemical transformations
… is central to understanding effects from the molecular to … to observe single molecules and
study nanoconfined dynamic … a preferred molecular orientation but the random molecular …
study nanoconfined dynamic … a preferred molecular orientation but the random molecular …
Nanoconfinement raises the energy barrier to hydrogen atom exchange between water and glucose
SL Miller, BP Wiebenga-Sanford… - The Journal of …, 2021 - ACS Publications
… a model to increase understanding of a wide … of nanoconfinement could be used to introduce
energy barriers that allow for the study of previously unobserved high energy intermediates …
energy barriers that allow for the study of previously unobserved high energy intermediates …