Efficient ammonia synthesis over phase-separated nickel-based intermetallic catalysts

TN Ye, Y Lu, Y Kobayashi, J Li, SW Park… - The Journal of …, 2020 - ACS Publications
… to those of reported Ru-based intermetallic catalysts. TEM … were self-organized during ammonia
synthesis and generated a Ni–… a series of intermetallic compounds (YRu 2 , LaCoSi, and …

Review on catalytic roles of rare earth elements in ammonia synthesis: Development and perspective

L Li, T Zhang, Y Zhou, X Wang, C Au, L Jiang - Journal of Rare Earths, 2022 - Elsevier
… 3 synthesis, including that as promoter, support, intermetallic … Y increased the electron density
of Ru species, resulting in … bulk YRu 2 (0.01918 s −1 ) and the laser-ablated YRu 2 sample …

Zr-based Laves phases with nitride/hydride ions for ammonia synthesis

Y Cao, Z Wei, W Al Maksoud, R Rai, Y Kobayashi… - Solid State …, 2023 - Elsevier
… Recently, YRu 2 intermetallic hydride has been developed … increases the electron density
over Ru and therefore … the activity of the well-established Ru catalyst Cs–Ru/MgO (2.7 mmol g −…

Nature of reactive hydrogen for ammonia synthesis over a Ru/C12A7 electride catalyst

J Kammert, J Moon, Y Cheng, L Daemen… - Journal of the …, 2020 - ACS Publications
… The presence of electrons with low work functions is proposed to promote ammonia synthesis
in a similar manner to the promotion of Ru by basic metals, by donating electron density

Rare‐earth incorporated alloy catalysts: Synthesis, properties, and applications

S Zhang, SE Saji, Z Yin, H Zhang, Y Du… - Advanced …, 2021 - Wiley Online Library
application of RE alloys in the field of ammonia synthesis (Table 3). … ) intermetallic bulk
catalyst YRu 2 is reported. [ 128 ] The electron density eventually forms a negatively charged Ru

Ammonia as a carrier of renewable energy: Recent progress of ammonia synthesis by homogeneous catalysts, heterogeneous catalysts, and electrochemical method

T Ogawa - Emerging Trends to Approaching Zero Waste, 2022 - Elsevier
… Promotors such as K 2 O and CaO increase the electron density of the catalyst. The added
… is the Laves phase intermetallic catalyst, YRu 2 , where electron transfers from Y to Ru. …

Low Apparent Activation Energy of Ammonia Synthesis over Ru Catalyst Supported by Hydrogen Storage Material

R Morimoto, T Ogawa, K Torii, T Seno, H Okumura… - 2023 - chemrxiv.org
… For 7wt%Ru0.2K/ZrH2, the improved activity is attributed to the … Ru+K showed the highest
activity among the catalysts tested in … High Electron Density on Ru in Intermetallic YRu2: The …

Development and recent progress on ammonia synthesis catalysts for Haber–Bosch process

J Humphreys, R Lan, S Tao - Advanced Energy and …, 2021 - Wiley Online Library
… promoted-Ru catalysts for existing ammonia synthesis plants and future distributed green
ammonia synthesis based … [ 102 ] Other catalysts to use this design include intermetallic YRu 2

12.1 Importance of ammonia

T Ogawa - Emerging Trends to Approaching Zero Waste …, 2021 - books.google.com
… for NH3 synthesis over heterogeneous catalysts, with the example of Fe-based … High
electron density on Ru in intermetallic YRu2: The application to catalyst for ammonia synthesis

Economies of scale in ammonia synthesis loops embedded with iron-and ruthenium-based catalysts

M Yoshida, T Ogawa, Y Imamura… - International Journal of …, 2021 - Elsevier
… in ammonia synthesis loops embedded with Ru/C. As a comparison, the loops with the
commercialized iron-based catalysts, … and changed the amount of ammonia production scale. We …