In this study, a series of Bi₂O₃ reinforced bariumtelluroborate (TBX) glasses with the nominal composition 20TeO₂ + (50-x)B₂O₃ + 29.5BaO + xBi₂O₃ + 0.5Er₂O₃ (where x=0,5,10,15 and 20 in wt%) were manufactured using traditional melt-quenching method. The structural and compositional studies were performed by using XRD and FTIR spectra. In general, the glass matrix consists of the trigonal-planar and tetrahedral units of borates, tellurate and tellurite groups of tellurites, and the non-bridging oxygen (nBO). In addition to that, BiO₃ and BiO₆ groups are present in top-order glasses. The gamma-ray shielding (γ-RS) ability was evaluated through the vital parameters like the mass-attenuation coefficient (MAC), mean free-path (MFP), half-value layer (HVL), and effective atomic-number (Z_eff). TB20 glass is happened to be the best candidate by giving the highest value for MAC and the lowest MFP and HVL, owing to its large density, 6.922 g/cm³. The fast neutron-removal cross-section (∑R) is assessed to investigate the neutron shielding capacity of TBX glasses. The γ-rays shielding properties of TBX glasses were observed better than some ordinary shields such as barite-concrete and commercial shielding glasses developed by SCHOTT Company.