… and theoretical insights into the electronic properties of anionic N-heterocyclic dicarbenes through the rational synthesis of their transition metal complexes
AA Grineva, OA Filippov, Y Canac, JB Sortais… - Inorganic …, 2021 - ACS Publications
… I (14) NHC backbone bond activation in bidentate and pincer … interactions in half-sandwich
carbene complexes, (27c) we … potential of metal NHC complexes constitutes an alternative, …
carbene complexes, (27c) we … potential of metal NHC complexes constitutes an alternative, …
Recent progress on NHC-stabilized early transition metal (group 3–7) complexes: Synthesis and applications
C Romain, S Bellemin-Laponnaz, S Dagorne - Coordination Chemistry …, 2020 - Elsevier
… of IMes to the Y(III) center followed by a sterically driven normal-to-abnormal NHC rearrangement.
Though such … Among group 4 carbene complexes, group 4 metal complexes stabilized …
Though such … Among group 4 carbene complexes, group 4 metal complexes stabilized …
NHC-stabilized Alanes and Gallanes
A Hock - 2021 - opus.bibliothek.uni-wuerzburg.de
… undergoes a normal-to-abnormal NHC rearrangement to the … monomeric three-coordinate
dicationic aluminium complex. … bond activation with insertion of the Al-H moiety into the NHC …
dicationic aluminium complex. … bond activation with insertion of the Al-H moiety into the NHC …
Divergent Interaction of (Iso) nitriles with a Linear Iron (I) Silylamide─ A Combined Structural, Spectroscopic, and Computational Study
CG Werncke, I Müller, K Weißer… - Inorganic Chemistry, 2024 - ACS Publications
… to a substantial bond activation via d → π… Fe II ion is preferred. Contrastingly, aliphatic
isonitriles are cleaved to give a 1:1 mixture of a rare iron(II) cyanide and an organo iron(II) complex…
isonitriles are cleaved to give a 1:1 mixture of a rare iron(II) cyanide and an organo iron(II) complex…
Quantifying the electronic and steric properties of 1, 3-imidazole-based mesoionic carbenes (iMICs)
A Merschel, D Rottschäfer, B Neumann… - …, 2020 - ACS Publications
… makes the C1 and C2 carbenes stronger σ donors than C3–C6. The N–C–N bond angle of
five-membered NHC C6 is more acute than that of the six-membered NHC C7, resulting in a …
five-membered NHC C6 is more acute than that of the six-membered NHC C7, resulting in a …
Cobalt (− I)-and rhodium (− I)-mediated dearylation of N-aryl N-heterocyclic carbene ligands
P Wang, J Cheng, D Wang, C Yang, X Leng… - …, 2020 - ACS Publications
… a new type of bond-activation reaction of NHCs: … ) complexes in the form of (NHC)M(η
2 -alkene) 2 . (8) Aiming to investigate the capability of this ligand set in stabilizing three-coordinate …
2 -alkene) 2 . (8) Aiming to investigate the capability of this ligand set in stabilizing three-coordinate …
Poly(imidazolyliden-yl)borato Complexes of Tungsten: Mapping Steric vs. Electronic Features of Facially Coordinating Ligands
CM Inglis, RA Manzano, RM Kirk, M Sharma… - Molecules, 2023 - mdpi.com
… ligands in an octahedral metal complex. N-heterocyclic carbenes (NHC) have emerged over
… led to a plethora of complexes that feature both NHC and conventional alkylidene ligands. …
… led to a plethora of complexes that feature both NHC and conventional alkylidene ligands. …
Cationic Organometallic Complexes of Group 12 Metals: A Decade of Progress Toward the Quest of Novel Lewis Acidic Catalysts
S Dagorne, P de Frémont, N Adet, J Parmentier… - Available at SSRN … - papers.ssrn.com
… The reaction is restricted to nucleophilic indoles activated … the observed normal-to-abnormal
NHC rearrangement to species 16… Complex 20 is the first example of a three-coordinate ZnII …
NHC rearrangement to species 16… Complex 20 is the first example of a three-coordinate ZnII …
Sequestering and metamorphosis of molecular nitrogen at ambient conditions: role of bonding and back-bonding
… motivates us to extend our studies with these carbenes for N2 activation. Since … with NHC
occurs through the σ electron ( σ2) donation of NHC to the π∗(0) of SO2.The reaction of NHC …
occurs through the σ electron ( σ2) donation of NHC to the π∗(0) of SO2.The reaction of NHC …
A structural and functional model for alkene dioxygenases
A Banerjee, AE Creek, AYS Malkhasian… - Journal of Inorganic …, 2024 - Elsevier
… of oxygen activation by cation 2 and corresponding oxidation … Coordination of a putative
oxygen to iron (as Fe III -OO⋅) in the … iron(III)-alkylperoxo intermediate which can then rearrange …
oxygen to iron (as Fe III -OO⋅) in the … iron(III)-alkylperoxo intermediate which can then rearrange …