… I (14) NHC backbone bond activation in bidentate and pincer … interactions in half-sandwich
carbene complexes, (27c) we … potential of metal NHC complexes constitutes an alternative, …

… of IMes to the Y(III) center followed by a sterically driven normal-to-abnormal NHC rearrangement.
Though such … Among group 4 carbene complexes, group 4 metal complexes stabilized …

… undergoes a normal-to-abnormal NHC rearrangement to the … monomeric three-coordinate
dicationic aluminium complex. … bond activation with insertion of the Al-H moiety into the NHC …

… to a substantial bond activation via d → π… Fe II ion is preferred. Contrastingly, aliphatic
isonitriles are cleaved to give a 1:1 mixture of a rare iron(II) cyanide and an organo iron(II) complex…

… makes the C1 and C2 carbenes stronger σ donors than C3–C6. The N–C–N bond angle of
five-membered NHC C6 is more acute than that of the six-membered NHC C7, resulting in a …

… a new type of bond-activation reaction of NHCs: … ) complexes in the form of (NHC)M(η
2 -alkene) 2 . (8) Aiming to investigate the capability of this ligand set in stabilizing three-coordinate …

… ligands in an octahedral metal complex. N-heterocyclic carbenes (NHC) have emerged over
… led to a plethora of complexes that feature both NHC and conventional alkylidene ligands. …

… The reaction is restricted to nucleophilic indoles activated … the observed normal-to-abnormal
NHC rearrangement to species 16… Complex 20 is the first example of a three-coordinate ZnII …

… motivates us to extend our studies with these carbenes for N2 activation. Since … with NHC
occurs through the σ electron ( σ2) donation of NHC to the π∗(0) of SO2.The reaction of NHC …

… of oxygen activation by cation 2 and corresponding oxidation … Coordination of a putative
oxygen to iron (as Fe III -OO⋅) in the … iron(III)-alkylperoxo intermediate which can then rearrange …