… single-molecule magnets with distinct energy barriers, which are caused by disparate substitutes
on the amidinate ligands. Single-molecule magnets … traverse its magnetization direction …

… Symmetry and axiality are thought to be guides toward the pursuit of high energy barrier and
blocking temperature for the dysprosium (III) (Dy III ) single-molecule magnets (SMMs). The …

… The use of bulky metallocene motifs in the design of mono- and multi-nuclear dysprosium
single-molecule magnets is described, as well as the use of bulky metallocenes in allowing the …

… Molecular design is crucial for improving the performance of single-molecule magnets (SMMs).
For dysprosium(III) SMMs, enhancing ligand-field axiality is a well-suited strategy to …

… , placing it among coveted dinuclear metallocene single-molecule magnets. CASSCF
calculations provided the energy of the crystal field states of Dy III and confirmed the barrier height. …

… This section introduces trivalent lanthanocene complexes that can function as single-molecule
magnets. Trivalent Ln-based complexes are excellent candidates for SMMs due to their …

… in the synthesis of high-performance single-molecule magnets (SMMs). These remarkable
… the potential to surpass the current records set by bis-cyclopentadienyl dysprosium SMMs. …

… Manipulating magnetic couplings in molecular magnets is of great importance in improving
… similar ferromagnetic couplings with comparable single-molecule magnetic behaviors. The …

… single-molecule magnets (SMMs) with a N1,N3-bis(3-methoxysalicylidene)diethylenetriamine
(H 2 L) ligand. Fortunately, an air-stable Dy 2 complex, [Dy 2 (L) 2 (tfac) 2 ] (1; Htfac = 1,1,1…

… features of classical hard magnets,36 and they offer a great case study for our aim. … H atoms
from the pyridinic groups and the bridging chlorides and in-plane terminal chloro ligands are …