Protein-protein interactions are spatially regulated in living cells to realize high reaction
efficiency, as seen in naturally existing electron-transfer chains. Nevertheless, arrangement …

The high plasticity of the active-site cavity of cytochromes P450, permitting reactivity toward
a vast array of compounds, makes these enzymes attractive targets for biotechnological …

Advances in synthetic biology permit the genetic encoding of synthetic chemistries at
monomeric precision, enabling the synthesis of programmable proteins with tunable …

Conspectus Many artificial enzymes that catalyze redox reactions have important energy,
environmental, and medical applications. Native metalloenzymes use a set of redox-active …

A common bioelectronics goal is to enable communication between biology and electronics,
and success is critically dependent on the communication modality. When a biorelevant …

Electrically conductive filaments from Geobacter sulfurreducens were reported to be pili with
metallic-like conductivity, and yet were later shown to be redox-active cytochromes by …

Building up efficient electronic nanodevices by profiting from nature optimized biomolecular
machinery is a clear challenge for today's scientific and engineering communities [1] …

Multi-heme cytochrome c (Cytc) proteins are key for transferring electrons out of cells, to
enable intracellular oxidation to proceed in the absence of O2. In these proteins most of the …

The emerging field of BioMolecular Electronics aims to unveil the charge transport
characteristics of biomolecules with two primary outcomes envisioned. The first is to use …

Real-time chemical sensing is needed to counter the global threats posed by pollution. We
combine synthetic biology and materials engineering to develop a living bioelectronic …