[HTML][HTML] Population and coherence dynamics in large conjugated porphyrin nanorings

G Bressan, M Jirasek, P Roy, HL Anderson… - Chemical …, 2022 - pubs.rsc.org
In photosynthesis, nature exploits the distinctive electronic properties of chromophores
arranged in supramolecular rings for efficient light harvesting. Among synthetic …

Exciton–Exciton Annihilation as a Probe of Exciton Diffusion in Large Porphyrin Nanorings

G Bressan, M Jirasek, HL Anderson… - The Journal of …, 2020 - ACS Publications
The photophysical behavior of natural and artificial cyclic supramolecular structures has
been intensively investigated in the past decade. Among the artificial structures, large fully π …

Time-resolved structural dynamics of extended π-electron porphyrin nanoring

G Bressan, MD Peeks, HL Anderson… - The Journal of …, 2019 - ACS Publications
The design of molecular structures inspired by naturally occuring light harvesting systems
has been intensely pursued over the last couple of decades. Interesting new structures …

Excitation energy transport processes of porphyrin monomer, dimer, cyclic trimer, and hexamer probed by ultrafast fluorescence anisotropy decay

HS Cho, H Rhee, JK Song, CK Min… - Journal of the …, 2003 - ACS Publications
Femtosecond fluorescence anisotropy measurements for a variety of cyclic porphyrin arrays
such as ZnIIporphyrin m-trimer and hexamer are reported along with o-dimer and monomer …

Discrimination of diverse coherences allows identification of electronic transitions of a molecular nanoring

V Butkus, J Alster, E Bašinskaitė… - The Journal of …, 2017 - ACS Publications
The role of quantum coherence in photochemical functions of molecular systems such as
photosynthetic complexes is a broadly debated topic. Coexistence and intermixing of …

Exciton level structure and dynamics in tubular porphyrin aggregates

Y Wan, A Stradomska, S Fong, Z Guo… - The Journal of …, 2014 - ACS Publications
We present an account of the optical properties of the Frenkel excitons in self-assembled
porphyrin tubular aggregates that represent an analog to natural photosynthetic antennae …

Aromaticity and antiaromaticity in the excited states of porphyrin nanorings

MD Peeks, JQ Gong, K McLoughlin… - The Journal of …, 2019 - ACS Publications
Aromaticity can be a useful concept for predicting the behavior of excited states. Here we
show that π-conjugated porphyrin nanorings exhibit size-dependent excited-state global …

Breaking the symmetry in molecular nanorings

JQ Gong, L Favereau, HL Anderson… - The Journal of Physical …, 2016 - ACS Publications
Because of their unique electronic properties, cyclic molecular structures ranging from
benzene to natural light-harvesting complexes have received much attention. Rigid π …

Ultrafast dynamics of highly conjugated porphyrin arrays

R Kumble, S Palese, VSY Lin, MJ Therien… - Journal of the …, 1998 - ACS Publications
The photophysical properties of a series of ethynyl-bridged (porphinato) zinc (II) oligomers
have been investigated over the femtosecond and picosecond time scales using ultrafast …

Dynamics of excited-state conformational relaxation and electronic delocalization in conjugated porphyrin oligomers

MH Chang, M Hoffmann, HL Anderson… - Journal of the American …, 2008 - ACS Publications
We have investigated the influence of nuclear geometric relaxation on the extent of the
excited-state electronic delocalization in conjugated zinc porphyrin oligomers using ultrafast …