We here present how rebalancing the interplay between H‐bonds and dispersive forces
(Van der Waals/π–π stacking) may induce or not the generation of kinetic metastable states …

The prevalence of kinetically accessible states in supramolecular polymerization pathways
has been exploited to control the growth of the polymer and thereby to obtain niche …

We reveal unique hydrogen (H‐) bonding patterns and exploit them to control the kinetics,
pathways and length of supramolecular polymers (SPs). New bisamide‐containing …

Cooperative π–π interactions and H‐bonding are frequently exploited in supramolecular
polymerization; however, close scrutiny of their mutual interplay has been largely …

After more than three decades of extensive investigations on supramolecular polymers,
strategies for self‐limiting growth still remain challenging. Herein, we exploit a new V …

We have investigated the kinetic and thermodynamic supramolecular polymerizations of a
series of amide-functionalized perylene bisimide (PBI) organogelator molecules bearing …

Pathway complexity, hierarchical organization, out of equilibrium, and metastable or
kinetically trapped species are common terms widely used in recent, high‐quality …

Supramolecular polymerization has been traditionally focused on the thermodynamic
equilibrium state, where one-dimensional assemblies reside at the global minimum of the …

Chemical fuel-driven supramolecular systems have been developed showing out-of-
equilibrium functions such as transient gelation and oscillations. However, these systems …

While the mechanism of self-assembly of π-conjugated molecules has been well studied to
gain control over the structure and functionality of supramolecular polymers, the …