Cascade reactions catalyzed by immobilized multienzymatic systems are an emerging
technology, making catalytic strategies more sophisticated and effective. Thus, immobilized …

The surface chemistry, pendent functional entities, and ease in tunability of various materials
play a central role in properly coordinating with enzymes for immobilization purposes. Due …

Chemical modification and immobilization of enzymes have been usually considered
unrelated tools to improve biocatalyst features. However, there are many examples where a …

Industrial biocatalysis is playing a key role in the development of the global bio‐economy
that must change our current productive model to pair the socio‐economical development …

Application of industrial enzymes for production of valuable chemical compounds has
greatly benefited from recent developments in Systems and Synthetic Biology. Both, in vivo …

Re-engineering enzymes with high activities in the given environments different from the
physiological one has been constantly pursued for application of enzymatic catalysis in …

Sequential enzymes in a biosynthetic pathway often self-assemble to form nanomachineries
known as multienzyme complexes inside cells. Enzyme self-assembly insulates toxic …

Highlights•This review focuses on the self-assembly of enzyme and protein
complexes.•Naturally occurring enzyme complexes and scaffolds were discussed.•Main …

Enzymes are the prime protagonists in the chemistry of living organisms. As such, chemists
and biologists have long been fascinated by the array of highly selective transformations …

Biocatalytic cascades represent an attractive approach for the synthesis of valuable
chemicals. To be competitive with chemical synthesis, cascade reactions need to be …