Ferrocenyl-Substituted Triazatruxenes: Synthesis, Electronic Properties, and the Impact of Ferrocenyl Residues on Directional On-Surface Switching on Ag (111)

L Vogelsang, T Birk, F Paschke, A Bauer… - Inorganic …, 2023 - ACS Publications
We report on seven new ferrocenyl-(1, 3)-and ferrocenylethynyl-modified N, N′, N ″-
triethyltriazatruxenes (Et TAT s) 4–7 as well as the dodecyl counterpart 2 of compound 1 and …

Adamantane-based tripodal thioether ligands functionalized with a redox-active ferrocenyl moiety for self-assembled monolayers

T Weidner, M Zharnikov, DG Castner… - The Journal of …, 2010 - ACS Publications
Self-assembled monolayers (SAMs) can decorate surfaces with “smart” functional units
possessing reversible stimulus-response behavior for optical, thermal, magnetic, or redox …

Tip‐Induced Inversion of the Chirality of a Molecule's Adsorption Potential Probed by the Switching Directionality

A Bauer, M Maier, WM Schosser, J Diegel… - Advanced …, 2020 - Wiley Online Library
The switching behavior of surface‐supported molecular units excited by current, light, or
mechanical forces is determined by the shape of the adsorption potential. The ability to tailor …

Ferrocene and tetrathiafulvalene redox interplay across a bis-acetylide–ruthenium bridge

A Vacher, F Barriere, D Lorcy - Organometallics, 2013 - ACS Publications
The interplay between two different peripheral electrophores, ferrocene (Fc) and
tetrathiafulvalene (TTF), across a bis-acetylide ruthenium organometallic bridge has been …

A rotaxane scaffold bearing multiple redox centers: synthesis, surface modification and electrochemical properties

M Steffenhagen, A Latus, TMN Trinh… - … A European Journal, 2018 - Wiley Online Library
A rotaxane scaffold incorporating two dithiolane anchoring units for the modification of gold
surfaces has been functionalized with multiple copies of a redox unit, namely ferrocene …

Ferrocene-Based Nanoelectronics: Regioselective Syntheses and Electrochemical Characterization of α-Monothiol and α, ω-Dithiol, Phenylethynyl-Conjugated, 2, 5 …

C Engtrakul, LR Sita - Organometallics, 2008 - ACS Publications
Regiospecific synthetic methods have been developed for the assembly of unsymmetric
conjugated molecular frameworks containing 2, 5-diethynylpyridyl-and 2, 5 …

Solution and surface-confined chloride anion templated redox-active ferrocene catenanes

NH Evans, H Rahman, AV Leontiev, ND Greenham… - Chemical …, 2012 - pubs.rsc.org
The first examples of ferrocene containing catenanes, in solution and assembled on a
surface are described. Chloride anion templation is exploited to synthesize redox-active [2] …

Avoiding problem reactions at the ferrocenyl-alkyne motif: a convenient synthesis of model, redox-active complexes for molecular electronics

MS Inkpen, AJP White, T Albrecht, NJ Long - Dalton Transactions, 2014 - pubs.rsc.org
Avoiding problem reactions at the ferrocenyl-alkyne motif: a convenient synthesis of model,
redox-active complexes for molecular electronics - Dalton Transactions (RSC Publishing) …

Electroactive self-assembled monolayers on gold via bipodal dithiazepane anchoring groups

PA Bertin, D Georganopoulou, T Liang, AL Eckermann… - Langmuir, 2008 - ACS Publications
Novel dithiazepane-functionalized ferrocenyl-phenylethynyl oligomers 1 and 2 have been
synthesized. Self-assembled monolayers (SAMs) of these ferrocene derivatives have been …

Tailoring electronic states of a single molecule using adamantane-based molecular tripods

S Katano, Y Kim, T Kitagawa, M Kawai - Physical Chemistry Chemical …, 2013 - pubs.rsc.org
Adsorption structures and electronic states of molecular tripods, having a Br atom (BATT)
and a ferrocene derivative (Ferrocene-ATT) at the head part of the adamantane-based …