Direct Observation of Distinctive Electronic States of Ferrocene Moieties in Ferrocene-Bridged Trisporphyrin on Au (111) Using Scanning Tunneling Microscopy …

H Tanaka, A Satake, M Taniguchi - Langmuir, 2021 - ACS Publications
The mechanical and electronic properties of ferrocene-bridged trisporphyrin (Fc2P3), which
consists of three porphyrin units bridged via a ferrocene (Fc) moiety and adsorbed onto Au …

Photoswitching activation of a ferrocenyl-stilbene analogue by its covalent grafting to gold

F Bejarano, D Gutiérrez, J Catalán-Toledo… - Physical Chemistry …, 2022 - pubs.rsc.org
Until now, surface-deposited stilbenes have been much less studied than other
photochromic systems. Here, an asymmetrically substituted styrene incorporating a redox …

Fully Reprogrammable 2D Array of Multi‐State Molecular Switching Units

A Bauer, T Birk, F Paschke, A Fuhrberg… - Advanced …, 2024 - Wiley Online Library
Integration of molecular switching units into complex electronic circuits is considered to be
the next step towards the realization of novel logic and memory devices. Here, we report on …

Atropisomeric 3, 3′, 4, 4′, 5, 5′-hexaferrocenyl-2, 2′-bithiophene: synthesis, solid-State structure, and electrochemistry

JM Speck, D Schaarschmidt, H Lang - Organometallics, 2012 - ACS Publications
3, 3′, 4, 4′, 5, 5′-Hexaferrocenyl-2, 2′-bithiophene (4) has been prepared using a
straightforward synthesis protocol that follows the palladium-promoted Negishi cross …

Functionalization at nonperipheral positions of triazatruxene: modular construction of 1, 6, 11-triarylated-triazatruxenes for potentially organic electronics and …

M Aslan, Y Taskesenligil, S Pıravadılı… - The Journal of Organic …, 2021 - ACS Publications
Functionalization from nonperipheral positions of triazatruxene is representing a challenge.
Triarylation of the nonperipheral positions (1, 6, and 11) in triazatruxene scaffold has been …

Head-on versus Side-on [5− 5] Bitrovacenes Featuring Benzene and Naphthalene Units as Spacers: How π-Stacking Affects Exchange Coupling and Redox Splitting

C Elschenbroich, M Wolf, O Schiemann, K Harms… - …, 2002 - ACS Publications
The biradicals 1, 8-di ([5] trovacenyl) naphthalene (6), 1, 5-di ([5] trovacenyl) naphthalene
(7), and 1, 3-di ([5] trovacenyl) benzene (8) and the monoradical 1-[5] …

Diferrocenylbispyrylium salts and electron-rich diferrocenylbispyran from oxidative coupling of ferrocenylpyran. induced electron transfer C− C bond making/breaking …

F Ba, N Cabon, F Robin-Le Guen, P Le Poul… - …, 2008 - ACS Publications
Electrochemical or chemical dimerization of electron-rich ferrocenylmethylenepyran 1 gave
the first dimetallocenylbispyrylium salt 2 known today, through a reverse process that implies …

Noncovalent assembly of ferrocene on modified gold surfaces mediated by uracil–adenine base pairs

B Fabre, S Ababou-Girard, P Singh, J Kumar… - Electrochemistry …, 2010 - Elsevier
Redox-active ferrocene was assembled on gold surfaces through the hydrogen bonding
interactions between adenine-substituted ferrocene and a uracil-terminated organothiol …

Structures and properties of self-assembled monolayers of bistable [2] rotaxanes on Au (111) surfaces from molecular dynamics simulations validated with experiment

SS Jang, YH Jang, YH Kim, WA Goddard… - Journal of the …, 2005 - ACS Publications
Bistable [2] rotaxanes display controllable switching properties in solution, on surfaces, and
in devices. These phenomena are based on the electrochemically and electrically driven …

Molecular wires using (oligo) pyrroles as connecting units: An electron transfer study

U Pfaff, A Hildebrandt, D Schaarschmidt… - …, 2013 - ACS Publications
A series of (oligo) pyrroles featuring redox-active terminal ferrocenyl groups (Fc2-(c
C4H2NPh) n (4, n= 1; 9, n= 2; 16, n= 3; 20, n= 4)) has been prepared using a Negishi C, C …