Facile Syntheses of Trovacene, the Formation of [n]Boratrovacenophanes (n = 1, 2), and Their Reactivity toward [Pt(PEt3)4]

H Braunschweig, M Lutz, K Radacki… - …, 2006 - ACS Publications
Trovacene (1) was prepared by two novel procedures, employing readily available
vanadium precursors and after dimetalation converted into the [2] boratrovacenophane 2 …

Functionally rigid bistable [2] rotaxanes

S Nygaard, KCF Leung, I Aprahamian… - Journal of the …, 2007 - ACS Publications
Two-station [2] rotaxanes in the shape of a degenerate naphthalene (NP) shuttle and a
nondegenerate monopyrrolotetrathiafulvalene (MPTTF)/NP redox-controllable switch have …

Bipolar conductance switching of single anthradithiophene molecules

B Borca, V Schendel, R Pétuya, I Pentegov… - ACS …, 2015 - ACS Publications
Single molecular switches are basic device elements in organic electronics. The pentacene
analogue anthradithiophene (ADT) shows a fully reversible binary switching between …

Trovacenyl-based organometallic triradicals: Spin frustration, competing interactions and redox splitting

O Schiemann, J Plackmeyer, J Fritscher… - Applied Magnetic …, 2004 - Springer
Two new triradicals based on trovacene [η 7-tropylium) vanadium (η 5-cyclopentadienyl)], 1,
3, 5-tri ([5] trovacenyl) benzene 4 and 1, 3, 5-tri ([5] trovacenyl)-6-methoxybenzene 5 were …

Efficiency of π− π Tunneling in [2] Rotaxane Molecular Electronic Switches

YH Kim, WA Goddard - The Journal of Physical Chemistry C, 2007 - ACS Publications
We perform large-scale density functional and matrix Green's function calculations, and
study the coherent charge tunneling properties of molecular electronic devices based on the …

Absorption tuning of monosubstituted triazatruxenes for bulk heterojunction solar cells

T Bura, N Leclerc, S Fall, P Lévêque, T Heiser… - Organic …, 2011 - ACS Publications
A series of triazatruxene (TAT)-functionalized Bodipy dyes were prepared by a sequence of
reactions involving either cross-coupling reactions promoted by Pd complexes or a …

Kinetic dispersion in redox-active dithiocarbamate monolayers

AL Eckermann, JA Shaw, TJ Meade - Langmuir, 2010 - ACS Publications
Dithiocarbamates (dtcs) have been implicated as important gold-binding groups in
molecular electronics. Dtcs have two alkane branches connected at a single anchoring point …

Synthesis of Functionalized Mono‐, Bis‐, and Trisethynyltriptycenes for One‐Dimensional Self‐Assembly on Surfaces

AM Sirven, R Garbage, Y Qiao… - … A European Journal, 2015 - Wiley Online Library
This paper describes the synthesis of triptycene‐based building blocks that are able to
interact through hydrogen bonds to form one‐dimensional self‐assembled motifs on …

Arylethynylanthraquinone and Bis (arylethynyl) anthraquinone: Strong Donor–Acceptor Interaction and Proton-induced Cyclization to Form Pyrylium and Dipyrylium …

R Sakamoto, KP Rao, H Nishihara - Chemistry letters, 2011 - academic.oup.com
In this account we describe ethynylene-conjugated arylethynylanthraquinone (ArAq) and bis
(arylethynyl) anthraquinone (Ar2Aq) which possess ferrocene, triarylamine, platinadithiolene …

(Multi) ferrocenyl five-membered heterocycles: excellent connecting units for electron transfer studies

A Hildebrandt, H Lang - Organometallics, 2013 - ACS Publications
The electro-and spectroelectrochemical behavior of diverse (multi) ferrocenyl five-
membered heterocyclic compounds, including furan, thiophene, pyrroles, phospholes, etc. is …