Solution and surface-confined chloride anion templated redox-active ferrocene catenanes

NH Evans, H Rahman, AV Leontiev, ND Greenham… - Chemical …, 2012 - pubs.rsc.org
The first examples of ferrocene containing catenanes, in solution and assembled on a
surface are described. Chloride anion templation is exploited to synthesize redox-active [2] …

Catenation through a combination of radical templation and ring-closing metathesis

IC Gibbs-Hall, NA Vermeulen, EJ Dale… - Journal of the …, 2015 - ACS Publications
Synthesis of an electrochemically addressable [2] catenane has been achieved following
formation by templation of a [2] pseudorotaxane employing radically enhanced molecular …

[引用][C] Redox‐functionalized Ligands: From Molecular Electrochemical Sensors to Nanostructured Surfaces

U Siemeling - Zeitschrift für anorganische und allgemeine …, 2005 - Wiley Online Library
The modification of ligands by functional groups can lead to novel, emergent ligand
properties. Our group has focussed on bi‐and tridentate N donor ligands which contain …

Electroactive self-assembled monolayers on gold via bipodal dithiazepane anchoring groups

PA Bertin, D Georganopoulou, T Liang, AL Eckermann… - Langmuir, 2008 - ACS Publications
Novel dithiazepane-functionalized ferrocenyl-phenylethynyl oligomers 1 and 2 have been
synthesized. Self-assembled monolayers (SAMs) of these ferrocene derivatives have been …

Conducting ferrocene monolayers on nonconducting surfaces

F Hauquier, J Ghilane, B Fabre… - Journal of the American …, 2008 - ACS Publications
The redox activity of a ferrocenyl monolayer grafted on an n-type Si (111) substrate was
investigated by scanning electrochemical microscopy (SECM) in conditions where the …

Ferrocene as an iconic redox marker: from solution chemistry to molecular electronic devices

G Roy, R Gupta, SR Sahoo, S Saha, D Asthana… - Coordination Chemistry …, 2022 - Elsevier
Ferrocene since its inception in the year 1951, has been extensively exploited as a crucial
redox probe to unravel electrochemical charge-transfer dynamics in a variety of platforms …

An anodic method for covalent attachment of molecules to electrodes through an ethynyl linkage

MV Sheridan, K Lam, WE Geiger - Journal of the American …, 2013 - ACS Publications
Electroactive organometallic molecules have been covalently attached to electrode surfaces
through an ethynyl linkage. The process takes advantage of ethynyl-based radicals …

[引用][C] An Electroactive Nitrogen‐Rich [4.4]Ferrocenophane Displaying Redox‐Switchable Behavior: Selective Sensing, Complexation, and Decomplexation of Mg2+ …

A Caballero, V Lloveras, A Tárraga… - Angewandte Chemie …, 2005 - Wiley Online Library
Redox-responsive ligands that contain a ferrocene unit as the redox-active group have been
one of the most extensively studied groups among the numerous examples of these …

On-surface cross-coupling methods for the construction of modified electrode assemblies with tailored morphologies

AAS Gietter, RC Pupillo, GPA Yap, TP Beebe… - Chemical …, 2013 - pubs.rsc.org
Controlling the molecular topology of electrode–catalyst interfaces is a critical factor in
engineering devices with specific electron transport kinetics and catalytic efficiencies. As …

Sterically Controlled Functionalization of Carbon Surfaces with −C6H4CH2X (X = OSO2Me or N3) Groups for Surface Attachment of Redox-Active Molecules

W Liu, TD Tilley - Langmuir, 2015 - ACS Publications
Glassy carbon electrodes were modified by electrochemical reduction of a diazonium
molecule (i Pr3SiOCH2C6H4N2+ BF4–) featuring a triisopropylsilyl-protected benzylic …