Separation, identification, and confirmation of cyclic and tadpole macromolecules via UPLC-MS/MS

JM O'Neill, J Mao, FM Haque, F Barroso-Bujans… - Analyst, 2022 - pubs.rsc.org
Macrocyclic poly (glycidyl phenyl ether)(pGPE) synthesized via zwitterionic ring opening
polymerization is typically contaminated by chains with linear and tadpole architecture …

Detection, quantification, and “click-scavenging” of impurities in cyclic poly (glycidyl phenyl ether) obtained by zwitterionic ring-expansion polymerization with B (C6F5) …

FM Haque, A Alegria, SM Grayson… - …, 2017 - ACS Publications
The physical properties of cyclic polymers can be perturbed by the presence of architectural
impurities, even in trace amounts. As a result, it is important to develop techniques for …

Well-defined cyclic polymer synthesis via an efficient etherification-based bimolecular ring-closure strategy

S Sharma, K Ntetsikas, V Ladelta, S Bhaumik… - Polymer …, 2021 - pubs.rsc.org
The synthesis of cyclic polymers on a large scale is a challenging task for polymer scientists
due to the requirement of ultra-high dilution conditions. In this paper, we demonstrate an …

Synthesis and characterization of ring-shaped polystyrenes

B Lepoittevin, MA Dourges, M Masure, P Hemery… - …, 2000 - ACS Publications
Macrocyclic polystyrenes were prepared by coupling a two-ended living precursor dianions
with 1, 3-bis (1-phenylethylenyl) benzene (DDPE). Experiments were performed in a drybox …

Multidimensional mass spectrometry methods for the structural characterization of cyclic polymers

AM Yol, C Wesdemiotis - Reactive and Functional Polymers, 2014 - Elsevier
Several synthetic methods have been developed for the tailored preparation of cyclic
macromolecules due to their unique physical and chemical properties. Unequivocal …

Synthesis and characterization of novel cyclic (aryl ether ketone) s, cyclic (aryl ether phthalazine) s, and cyclic (aryl ether isoquinoline) s

KP Chan, YF Wang, AS Hay, XL Hronowski… - …, 1995 - ACS Publications
The efficient preparation of a range of cyclic (aryl ether ketone) s containing the 1, 2-
dibenzoylbenzene moiety via the nucleophilic aromaticsubstitution route with the use of the …

Understanding zwitterionic ring‐expansion polymerization through mass spectrometry

M Ahmad, SM Grayson - Mass Spectrometry Reviews, 2024 - Wiley Online Library
Zwitterionic ring‐expansion polymerization (ZREP) is a polymerization method in which a
cyclic monomer is converted into a cyclic polymer through a zwitterionic intermediate. In this …

Novel macrocyclic precursors of phenolphthalein poly (arylene ether ketone) and poly (arylene ether sulfone): Synthesis and polymerization

H Jiang, T Chen, S Bo, J Xu - Macromolecules, 1997 - ACS Publications
Introduction. In recent years, the advantages of using cyclic (arylene ether ketone) s1-16 and
cyclic (arylene ether sulfone) s12, 16-22 as precursors of high-performance thermoplastics …

Differentiation of Linear and Cyclic Polymer Architectures by MALDI Tandem Mass Spectrometry (MALDI-MS2)

AM Yol, DE Dabney, SF Wang, BA Laurent… - Journal of The …, 2012 - ACS Publications
[M+ Ag]+ ions from cyclic and linear polystyrenes and polybutadienes, formed by matrix-
assisted laser desorption ionization (MALDI), give rise to significantly different fragmentation …

The characterization of dendronized poly (ethylene glycol) s and poly (ethylene glycol) multi-arm stars using matrix-assisted laser desorption/ionization time-of-flight …

BK Myers, B Zhang, JE Lapucha, SM Grayson - Analytica Chimica Acta, 2014 - Elsevier
The synthesis of branched poly (ethylene glycol)(PEG) derivatives, namely star PEG and
dendronized PEG, can be challenging and their purity can be difficult to ascertain using …