Selective catalytic ozonation of gaseous ammonia to dinitrogen on cryptomelane-type manganese oxide catalysts: Role of oxygen vacancies and acid sites

L Wang, T Wen, H Dong, J Zhang, C Long - Journal of Cleaner Production, 2022 - Elsevier
Two kinds of cryptomelane-type manganese oxide (OMS-2-Ac and OMS-2-SO 4) catalysts
were prepared with MnAc 2· 4H 2 O and MnSO 4 as precursors, respectively, and were …

Insights into the influence of water molecules on selective catalytic ozonation of gaseous ammonia into nitrogen on cryptomelane-type manganese oxide using in-situ …

L Wang, L Gao, A Li, T Wen, J Zhang, C Long - Chemosphere, 2023 - Elsevier
Catalytic ozonation is an environmentally friendly technology for the removal of gaseous NH
3 due to high NH 3 conversion and high N 2 selectivity at ambient temperature. However …

Nitrogen promoted electron transfer to create highly active Cu2+ and Mn3+ sites for efficient catalytic ozonation of Ammonia over copper and nitrogen co-doped …

L Wang, Q Shao, T Wen, Y Ji, J Zhang… - Chemical Engineering …, 2024 - Elsevier
Eliminating ammonia (NH 3) from high-humidity exhaust gases by catalytic oxidation is a
great challenge, especially at low temperatures. Herein, Cu and N co-doped cryptomelane …

A new insight into catalytic ozonation of ammonia by MgO/Co3O4 composite: The effects, reaction kinetics and mechanism

Z Zhang, H Ai, ML Fu, Y Hu, J Liu, Y Ji… - Chemical Engineering …, 2021 - Elsevier
It is highly concerned to explore heterogeneous catalysts of metal oxides to remove NH 4+-
N in the wastewater, in which NH 4+-N can be greatly oxidized as gaseous nitrogen in the …

The Effects of Mn2+ Precursors on the Structure and Ozone Decomposition Activity of Cryptomelane-Type Manganese Oxide (OMS-2) Catalysts

C Wang, J Ma, F Liu, H He, R Zhang - The Journal of Physical …, 2015 - ACS Publications
The effects of Mn2+ precursors on the structure and ozone decomposition activity of
cryptomelane-type manganese oxide (OMS-2) catalysts were investigated under high …

Oxygen vacancies enhancing performance of Mg-Co-Ce oxide composite for the selective catalytic ozonation of ammonia in water

Z Zhang, H Ai, ML Fu, Y Hu, J Liu, Y Ji… - Journal of Hazardous …, 2022 - Elsevier
Catalytic ozonation based on heterogeneous metal oxides is a promising approach to
removing ammonia as gaseous nitrogen from water. Herein, MgO/Co 3 O 4/CeO 2 was …

Low-temperature conversion of ammonia to nitrogen in water with ozone over composite metal oxide catalyst

Y Chen, Y Wu, C Liu, L Guo, J Nie, Y Chen… - Journal of Environmental …, 2018 - Elsevier
As one of the most important water pollutants, ammonia nitrogen emissions have increased
year by year, which has attracted people's attention. Catalytic ozonation technology, which …

Co-doped cryptomelane-type manganese oxide in situ grown on a nickel foam substrate for high humidity ozone decomposition

H Liang, X Wang, H Wang, Z Qu - Journal of Environmental Sciences, 2025 - Elsevier
Monolithic catalysts with excellent O 3 catalytic decomposition performance were prepared
by in situ loading of Co-doped KMn 8 O 16 on the surface of nickel foam. The triple-layer …

Simultaneous catalytic ozonation of NO and dichloromethane on Mn/H-ZSM-5 catalysts: Interaction effect and mechanism

H Tang, Y He, F Lin, Y Zhu, Y Duan, Z Wang - Proceedings of the …, 2023 - Elsevier
Catalytic ozonation is a promising method for simultaneous removal of NO x and Cl-VOCs,
but needs to clarify their interaction mechanism and the influence of catalyst acidity. In this …

Nonradical-dominated pathway toward selective catalytic ozonation of NH4+-N to N2 in drinking water over birnessite

C Zhang, C Shen, Z Huang, H Xu, Y Zeng… - Separation and …, 2024 - Elsevier
Abstract Ammonia nitrogen (NH 4+-N), which exists in the dominant form of ammonium ion
(NH 4+) under the pH of 6.5–8.5, is one of the regular indexes and the most important …