Characterization and Structural Classification of Heteroatom Components of Vacuum-Residue-Derived Asphaltenes Using APPI (+) FT-ICR Mass Spectrometry

JW Park, Y Cho, S Son, S Kim, KB Lee - Energy & Fuels, 2021 - ACS Publications
Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) has been widely
used as a major breakthrough to investigate the structure of asphaltenes in heavy oils. In this …

Structural information of asphaltenes derived from petroleum vacuum residue and its hydrotreated product obtained by FT-ICR mass spectrometry with narrow ion …

W Wang, M Dong, C Song, X Cai, Y Liu, Z Liu, S Tian - Fuel, 2018 - Elsevier
Petroleum asphaltene is a complex natural organic mixture which plays a crucial role in the
refining processes. In this work, asphaltenes derived from petroleum vacuum residue and its …

Separation and characterization of petroleum asphaltene fractions by ESI FT-ICR MS and UV-vis spectrometer

SS Wang, C Yang, CM Xu, SQ Zhao, Q Shi - Science China Chemistry, 2013 - Springer
Using heptane, toluene, and tetrahydrofuran (THF) as eluant, asphaltenes were fractionated
into five fractions based on their polarity and solubility. The molecular composition of polar …

Structural comparison of asphaltenes of different origins using multi-stage tandem mass spectrometry

W Tang, MR Hurt, H Sheng, JS Riedeman… - Energy & …, 2015 - ACS Publications
In this work, six petroleum asphaltene samples of different geographical origins were
studied using atmospheric pressure chemical ionization (APCI) in positive-ion mode in a …

Laser desorption ionization and collision induced dissociastion as powerful tools for FT-ICR mass spectrometric characterization of asphaltene fractions enriched in …

LC da Silva, JV Dávila, FP Fleming, MY Combariza… - Fuel, 2022 - Elsevier
Due to advances in mass spectrometry, it is widely accepted that asphaltenes molecules
from the island and archipelago motifs coexist in the samples. However, analyzing …

Architecture of miscellaneous asphaltenes: A molecular odyssey

JS Ramírez-Pradilla, J Rubiano, FA Rojas-Ruiz… - Fuel, 2024 - Elsevier
The advanced characterization of asphaltenes has been extensive and fruitful during the last
two decades but with many gaps. Despite the efforts to reveal the molecular architectures …

Comprehensive Characterization of Asphaltenes by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry Precipitated under Different n-Alkanes Solvents

MA Pudenzi, JM Santos, A Wisniewski Jr… - Energy & …, 2018 - ACS Publications
Asphaltenes are still problematic fractions and their composition is not fully unveiled as it
relates to the original crude oil and the precipitation method. In this work, the composition of …

Advances in asphaltene petroleomics. Part 2: selective separation method that reveals fractions enriched in island and archipelago structural motifs by mass …

ML Chacón-Patiño, SM Rowland, RP Rodgers - Energy & fuels, 2018 - ACS Publications
Advances in high-resolution Fourier transform ion cyclotron resonance mass spectrometry
(FT-ICR MS) enable molecular-level characterization of ultracomplex asphaltene samples …

Investigation of island/single-core-and archipelago/multicore-enriched asphaltenes and their solubility fractions by thermal analysis coupled with high-resolution …

A Neumann, ML Chacon-Patino, RP Rodgers… - Energy & …, 2020 - ACS Publications
Despite extensive research, the molecular-level chemical characterization of asphaltenes, a
highly aromatic solubility fraction of petroleum, remains an analytical challenge. This fraction …

Analysis of Xinjiang asphaltenes using high precision spectroscopy

X Qiyong, K Wyclif, P Jingjun, R Xiong, W Deng… - RSC …, 2020 - pubs.rsc.org
Asphaltenes are known for causing flow assurance problems in numerous oil fields. In this
study we present a comparative spectroscopic analysis of Xinjiang heavy oil asphaltenes as …