Designing a molecular magnetic button based on 4d and 5d transition-metal phthalocyanines

P Ferriani, S Heinze, V Bellini - Scientific reports, 2017 - nature.com
… , we have devised a functional molecule exhibiting different magnetic states upon structural
… M-Phthalocyanine (MPc), where M is a transition-metal ion belonging to the 4d and 5d series…

Magnetism and magnetic anisotropy of transition metal-phthalocyanine molecules

J Hu, R Wu - arXiv preprint arXiv:1402.0278, 2014 - arxiv.org
… FePc molecules were found to switch their magnetic … potential candidates from 4d or 5d TM-Pc
molecules that have large spin… efforts for the design of innovative magnetic molecules and …

Smart ligands for efficient 3d-, 4d-and 5d-metal single-molecule magnets and single-ion magnets

PS Perlepe, D Maniaki, E Pilichos, E Katsoulakou… - Inorganics, 2020 - mdpi.com
… used to design and synthesize novel crystalline molecule-based materials exhibiting useful
molecular magnetic materials [19,20]. The focus of this review is on transition-metal SMMs …

Giant magnetocrystalline anisotropy of 5d transition metal-based phthalocyanine sheet

J Zhou, Q Wang, Q Sun, Y Kawazoe… - Physical Chemistry …, 2015 - pubs.rsc.org
molecule magnets based on 3d metals is small and in typical … Our interest in this paper is
to design poly-TMPc based … Compared with 3d/4d TM atoms, heavier 5d elements usually …

Controlling the magnetism of adsorbed metal–organic molecules

W Kuch, M Bernien - Journal of Physics: Condensed Matter, 2016 - iopscience.iop.org
transition metal porphyrin and phthalocyanine molecules … shell of Mn 2+ and the Eu 5d
electrons is held responsible for the … If the creativity in designing new molecules with interesting …

Single ion magnets from 3d to 5f: developments and strategies

M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
… SIMs, including 3d and 5d transition metal ions, 4f lanthanide ions, … ), was reported, strategies
of ligand field design have … 2 Tb] (Pc=dianion of phthalocyanine) was reported to exhibit a …

Synthesis and Characterization of 4d and 5d Cyanometallate Compounds for Molecular Magnetism

FJ Birk - 2019 - search.proquest.com
… compounds based on 4d and 5d transition metal ions. Since … magnetic hysteresis, the pursuit
of Single Molecule Magnets (… computing, and molecular refrigeration technologies. SMM …

[PDF][PDF] Introduction to Molecule based Nano magnetic Materials

T Gupta - 2015 - stxavierstn.edu.in
… and designing bulk magnets originating from molecules … focussed towards transition
metal based Single Ion Magnets (… ideais well illustrated by the dysprosium(III) bis(phthalocyanine) …

Magnetic moment is an effective descriptor for electrocatalytic nitrogen reduction reaction on two-dimensional organometallic nanosheets

D Deng, LM Yang - ACS Applied Materials & Interfaces, 2023 - ACS Publications
… Unexpectedly, the magnetic moment of the transition metal … The present study opens a
way toward the rational design of … N 2 molecule boosts the activation of the N 2 molecule and …

Ammonia synthesis using single-atom catalysts based on two-dimensional organometallic metal phthalocyanine monolayers under ambient conditions

CX Huang, G Li, LM Yang, E Ganz - ACS Applied Materials & …, 2020 - ACS Publications
… This work provides new insights into the rational design of NRR catalysts and explores … is
that the transition metal atom has both occupied and empty d orbitals and the N 2 molecule has …